Sodium metabisulfite 焦亚硫酸钠

CAS 7681-57-4 MFCD00167602

化学结构图

7681-57-4
SMILES: O=S([O-])S(=O)(=O)[O-].[Na+].[Na+]

化学属性

Mol. FormulaNa2O5S2
Mol. Weight190.11
Melting Point>300 °C
Density1.480
TSCAYes
SolubilityFreely soluble in water, glycerol. Slightly soluble in alcohol
Boiling Point150°C
Stability对湿度和空气敏感

别名和识别编码

Chemical NameSodium metabisulfite
MDL NumberMFCD00167602
CAS Number7681-57-4
Synonym Sodium metabisulfite {LY} Sodium metabisulfite {} {LY} Sodium metabisulfite {} {} {LY} Sodium metabisulfite {} {} {} {LY} Sodium metabisulfite {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {}
EC Number231-673-0
Merck Number14,8638
PubChem Substance ID656671
Chemical Name Translation焦亚硫酸钠
Wiswesser Line NotationNA2 S2-O3-Q2
LabNetwork Molecule IDLN00194236
InChIInChI=1S/2Na.H2O5S2/c;;1-6(2)7(3,4)5/h;;(H,1,2)(H,3,4,5)/q2*+1;/p-2
Canonical SMILES[Na].O=S(O)S(=O)(=O)O
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分类

  • {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Puriss p.a. ACS, Q-S, Puriss p.a. ACS
  • {SNA} Chemical Synthesis, Essential Chemicals, Inorganic Salts, Research Essentials, Salts, Sodium, Sodium Salts, Synthetic Reagents
  • {SNA} Analytical Reagents for General Use, Essential Chemicals, Puriss p.a. ACS, Q-S, Puriss p.a. ACS, Research Essentials, Salts, Sodium Salts, 分析/色谱, 分析试剂
  • {SNA} Chemical Synthesis, Inorganic Salts, Sodium, Synthetic Reagents

产品应用

  • 分析用。防腐 剂。还原剂。抗氧剂

相关文献及参考

  • Merck: 14,8638

安全信息

RTECSUX8225000
Safety Statements
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
Risk Statements
  • R31 Contact with acids liberates toxic gas 与酸接触释放出有毒气体
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
GHS Symbol
Precautionary statements
Signal word
Hazard statements
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
WGK Germany1
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
UN Number 2693
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry an
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 192 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   24,266,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 115 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 6,1418,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 910 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 31,120,1968

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 180 ug/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,1,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 179,159,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 200 ug/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,1,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 20 gm/kg
SEX/DURATION            : multigenerations
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - stillbirth
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 10,291,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 40 gm/kg
SEX/DURATION            : multigenerations
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #
   alive at weaning per # alive at day 4)
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 10,291,1972

其他信息

  • 有二氧化硫的气味。在空气中逐渐氧化为硫酸钠。在150℃以上分解。易溶于水(64g/100ml)和甘油,微溶于乙醇,水溶液呈酸性,固体时,本品为焦亚硫酸钠 (Na2S2O5)。溶于水时,得到 NaHSO3 。半数致死量(大鼠,静脉)115mg/kg。对皮肤和粘膜有刺激性。

系列性分类


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