2'-Chloroacetoacetanilide 2-氯乙酰乙酰替苯胺

CAS 93-70-9 MFCD00018224

化学结构图

93-70-9
SMILES: CC(=O)CC(=O)Nc1ccccc1Cl

化学属性

Mol. FormulaC10H10ClNO2
Mol. Weight212
Melting Point105-108
TSCAYes
Solubility不溶于水、乙醚，溶于乙醇。
Density1.1920

别名和识别编码

Chemical Name2'-Chloroacetoacetanilide
MDL NumberMFCD00018224
CAS Number93-70-9
Synonym 2'-chloroacetoacetanilide 2'-CHLOROACETOACETANILIDE 2'-Chloroacetoacetanilide 2'-氯-N-乙酰乙酰苯胺 2'-氯乙醯乙醯苯胺 2-氯乙酰基乙酰苯胺 2’-chloro-acetoacetanilid AAOCA ACETOACET-O-CHLORANILIDE ACETOACETYL-O-CHLOROANILINE Acetoacetic-o-chloroanilide Butanamide, N-(2-chlorophenyl)-3-oxo- Butaneamide, N-(2-chlorophenyl)-3-oxo- N-(2-Chlorophenyl)-3-oxobutyramide N-Acetoacetyl-2-chloroaniline N-乙酰乙酰邻氯苯胺 O-CHLOROACETOACETANILIDE TIMTEC-BB SBB000518 n-(2-chlorophenyl)-3-oxo-butaneamid 乙酰基乙酰邻氯苯胺 邻氯-N-乙酰乙酰苯胺 邻氯乙酰乙酰苯胺 邻氯乙酰基乙酰苯胺
EC Number202-269-1
Alfabeta NameCHLOROPHENYLOXOBUTANAMIDE N23()----
Reaxys-RN2212748
PubChem Substance ID87565715
Chemical Name Translation2-氯乙酰乙酰替苯胺
Beilstein Registry Number2212748
Wiswesser Line NotationGR BMV1V1
LabNetwork Molecule IDLN00176672
InChIInChI=1S/C10H10ClNO2/c1-7(13)6-10(14)12-9-5-3-2-4-8(9)11/h2-5H,6H2,1H3,(H,12,14)
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; amide; ketone; 1fragment

相关文献及参考

  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSAK4300000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Warnings IRRITANT 危化品目录(2015) 危险化学品
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 11600 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Blood - normocytic anemia
REFERENCE :
   LONZA# Personal Communication from LONZA Ltd., CH-4002, Basel, Switzerland
   Volume(issue)/page/year: 10JUL1981

其他信息

  • 急性毒性:口服-大鼠 LD50: 11600 毫克/公斤
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • Alfa Aesar:2'-氯乙酰乙酰替苯胺,98% 2'-Chloroacetoacetanilide, 98%(93-70-9)
  • 用途三:用作染料中间体，用于生产颜料黄10G、颜料黄GP，以及生产染料中间体1-（2-氯苯基）3-甲基-5-吡唑啉酮等，也可进一步生产中性染料，如中性亮黄3GL、中性深棕BRL、中性橙RL等。
  • 外观性质:白色结晶粉末。
  • 2'-氯-N-乙酰乙酰苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0624 2'-氯乙酰乙酰苯胺 2'-Chloroacetoacetanilide 500G 1260元 2014/06/02 C0624 2'-氯乙酰乙酰苯胺 2'-Chloroacetoacetanilide 25G 278元 2010/05/25 A18674 2'-氯乙酰乙酰替苯胺, 98% 2'-Chloroacetoacetanilide, 98% 25g 694元
  • 用途一:本品为染料、有机颜料、农药的中间体，主要用于1.3.5吡唑酮及汉沙黄10G1色淀等
  • 毒性分级:低毒
  • Sigma Aldrich:93-70-9(sigmaaldrich)
  • MSDS 信息:乙酰基乙酰邻氯苯胺(93-70-9).msds
  • 用途二:用作染料和颜料的中间体
  • TCI Shanghai:2'-氯乙酰乙酰苯胺 2'-Chloroacetoacetanilide,>;98.0%(T)(93-70-9)
  • 方法一:由邻氯苯胺与双乙烯酮反应而得。反应在乙醇介质中进行，在25-30℃缩合得精品，再经过滤、洗涤、干燥得成品。将邻氯苯胺溶解在苯中，滴加乙酰乙酸乙酯也可制得该品。原料消耗定额：邻氯苯胺（99%）625kg/t、双乙烯酮（96%）414kg/t、酒精（95%）200kg/t。
  • MOL 文件:93-70-9.mol
  • 下游产品:耐晒黄10G --> 酸性黄116
  • 灭火剂:二氧化碳、砂土、泡沫
  • 可燃性危险特性:遇热分解放出有毒氯化物和氧化氮气体
  • 上游原料:二乙烯酮 --> 2-氯苯胺 --> 甲烷 --> 乙酰氧基乙酸
  • 图谱信息:2'-氯-N-乙酰乙酰苯胺(93-70-9)核磁图( 1 HNMR) 2'-氯-N-乙酰乙酰苯胺(93-70-9)Raman光谱 2'-氯-N-乙酰乙酰苯胺(93-70-9)核磁图( 13 CNMR) 2'-氯-N-乙酰乙酰苯胺(93-70-9)质谱(MS) 2'-氯-N-乙酰乙酰苯胺(93-70-9)红外图谱(IR1) 2'-氯-N-乙酰乙酰苯胺(93-70-9)红外图谱(IR2)
  • 类别:有毒物品

系列性分类

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