1,2-Bis[(2S,5S)-2,5-Diethylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate 1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)

CAS 213343-64-7 MFCD01862465

化学结构图

213343-64-7
SMILES: [Rh+].CC[C@H]1CC[C@H](CC)P1C1C=CC=CC=1P1[C@H](CC[C@@H]1CC)CC.F[B-](F)(F)F.C1C[CH][CH]CC[CH][CH]1 |^1:32,33,36,37|

化学属性

Mol. FormulaC30H48BF4P2Rh
Mol. Weight660.36
Appearance red-orange xtl.
Stabilityair sensitive

别名和识别编码

Chemical Name1,2-Bis[(2S,5S)-2,5-Diethylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate
Synonym 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {} {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetra
CAS Number213343-64-7
Chemical Name Translation1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)
PubChem Substance ID329761249
MDL NumberMFCD01862465
Canonical SMILESFB(F)[F-].CC[C@H]1CC[C@H](CC)[P]1(C2=C3C=CC=C2)[Rh+][P]43[C@@H](CC)CC[C@@H]4CC.C5/C=C\CC/C=C\C5.[F-]
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes

相关文献及参考

  • 1. Sammet, B.; et al., A two step synthesis of a key unit B precursor of cryptophycins by asymmetric hydrogenation Beilstein J. Org. Chem. 7 , 243-245, (2011)
  • 2. Chaturvedula, P. V.; et al., Enantioselective synthesis of constrained phenylalanine analogues Tetrahedron Lett. 51 , 5588-5591, (2010)
  • 3. Guo, Y.; et al., A General Approach to the Synthesis of β2-Amino Acid Derivatives via Highly Efficient Catalytic Asymmetric Hydrogenation of α-Aminomethylacrylates Adv. Synth. Catal. 352 , 1539-1553, (2010)
  • 4. Nair, L. G.; et al., Design and synthesis of novel fluoro amino acids: synthons for potent macrocyclic HCV NS3 protease inhibitors Tetrahedron Lett. 51 , 3057-3061, (2010)
  • 5. Terauchi, T.; et al., Stereoselective Synthesis of Triply Isotope-Labeled Ser, Cys, and Ala: Amino Acids for Stereoarray Isotope Labeling Technology Org. Lett. 10 , 2785-2787, (2008)
  • 6. Qiu, L.; et al., Enantioselective hydrogenation of α-aminomethylacrylates containing a free N-H group for the synthesis of β-amino acid derivatives Proc. Natl. Acad. Sci. U. S. A. 104 , 16787-16792, (2007)
  • 7. Shang, G.; et al., Asymmetric hydrogenation of a-primary and secondary amino ketones: efficient asymmetric syntheses of (-)-arbutamine and (-)-denopamine Chem. Eur. J. 13 , 7780-7784, (2007)

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Safety Statements
Precautionary statements
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

系列性分类


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