2-Phenoxyethyl Chloride 2-氯苯乙醚

CAS 622-86-6 MFCD00018946

化学结构图

622-86-6
SMILES: ClCCOc1ccccc1

化学属性

Mol. FormulaC8H9ClO
Mol. Weight156.61
Refractive indexn20/D 1.534(lit.)
Boiling Point97-98°C at15 mmHg
Density1.129
Flash Point101 °C
TSCAYes
Melting Point23-25 °C
Appearance 固体。熔点28，沸点217-220℃，100-102℃（1.6kPa）。溶于苯、乙醚、乙醇。

别名和识别编码

Chemical Name2-Phenoxyethyl Chloride
CAS Number622-86-6
Synonym (2-Chloroethoxy)benzene {LY} (2-Chloroethoxy)benzene {} {LY} (2-Chloroethoxy)benzene {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} { {} {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Chloroethoxy)benzene {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00018946
PubChem Substance ID87565401
EC Number210-757-0
Beilstein Registry Number971048
Reaxys-RN971048
Chemical Name Translation2-氯苯乙醚
InChIKeyVQUYNUJARXBNPK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00223377
Canonical SMILESClCCOC1=CC=CC=C1
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分类

  • {SNA} Building Blocks, C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ether; 1fragment
  • Aromatics

相关文献及参考

  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
Signal word
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Hazard Codes Xi
UN Number 3265 UN 3265
Packing Groupn/a
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:622-86-6.mol
  • 用途二:驱肠虫药灭虫宁的中间体，与二甲胺反应可生成中间体苯氧基乙基二甲胺。
  • 下游产品:2-(2-氯乙氧基)苯磺酰胺 --> 1-(2-苯氧基乙基)哌嗪 --> 邻-(Β-氯乙氧基)-苯磺酰基异氰酸酯
  • 2-氯苯乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0240 β-氯苯乙醚 beta-Chlorophenetole 500ML 4150元 2014/06/02 C0240 β-氯苯乙醚 beta-Chlorophenetole 25ML 471元 2010/05/25 L11345 2-苯氧基乙基氯, 97% 2-Phenoxyethyl chloride, 97% 5g 353元
  • 图谱信息:2-氯苯乙醚(622-86-6)核磁图( 13 CNMR) 2-氯苯乙醚(622-86-6)核磁图( 1 HNMR) 2-氯苯乙醚(622-86-6)质谱(MS) 2-氯苯乙醚(622-86-6)Raman光谱 2-氯苯乙醚(622-86-6)红外图谱(IR1)
  • 上游原料:氯乙烷
  • Alfa Aesar:2-苯氧基乙基氯,97% 2-Phenoxyethyl chloride, 97%(622-86-6)
  • TCI Shanghai:β-氯苯乙醚 beta-Chlorophenetole,>;95.0%(GC)(622-86-6)
  • 用途一:用于萘法唑酮等原料药的合成
  • Sigma Aldrich:622-86-6(sigmaaldrich)
  • 方法一:由苯酚与二氯乙烷反应而得。将苯酚、氢氧化钠溶液及水加入高压釜内，搅拌均匀成苯酚钠溶液，加入二氯乙烷，在4h内升温到130℃，压力0.75-0.88MPa，反应3h。冷却到45℃，加碱液洗涤，静置分层，加盐酸于水层回收多余苯酚。油层用水流至pH值为7，蒸去二氯乙烷得粗品，再精馏即得本品。
  • F:10-21

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C9 - Ethers

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