Bromotris(Dimethylamino)Phosphonium Hexafluorophosphate 溴代三(二甲基氨基)磷六氟磷酸盐

CAS 50296-37-2 MFCD00191864

化学结构图

50296-37-2
SMILES: CN(C)[P+](Br)(N(C)C)N(C)C.F[P-](F)(F)(F)(F)F

化学属性

Mol. FormulaC6H18BrF6N3P2
Mol. Weight388
Melting Point>300
TSCANo

别名和识别编码

Chemical NameBromotris(Dimethylamino)Phosphonium Hexafluorophosphate
Synonym Bromotris(N-methylmethanaminato)-phosphorus hexafluorophosphate
MDL NumberMFCD00191864
PubChem Substance ID160870946
CAS Number50296-37-2
Reaxys-RN14221932
Chemical Name Translation溴代三(二甲基氨基)磷六氟磷酸盐
Beilstein Registry Number14221932
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分类

  • {SNA} Chemical Synthesis, Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
  • {SA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
  • {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents

相关文献及参考

  • 1. J. M. Garcia, et al., Org. Lett. 11 , 3826-3829, (2009)
  • 2. S. Bae and M. K. Lakshman, J. Org. Chem. 73 , 3707-3713, (2008)
  • 3. C. Mordant, et al., Tetrahedron 63 , 6115-6123, (2007)
  • 4. C. Salmi, et al., Lett. Org. Chem. 2 , 628-633, (2005)
  • 5. C. M. Taylor, et al., J. Org. Chem. 70 , 1306-1315, (2005)
  • 6. G. Depecker, et al., Org. Biomolecular Chem. 2 , 74-79, (2004)
  • FT-IR 2 (1), 1553:C / Structure Index 1 , 169:A:8

安全信息

GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H350 May cause cancer 可能致癌
Hazard Codes 8 T
WGK Germany3
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
UN Number 1759 3263
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R45 May cause cancer 可能致癌
Storage condition Light Sensitive
Packing GroupII
Hazard Class8

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Peptides - Biochemicals and Reagents
  4. Peptide Synthesis 多肽合成
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Coupling - Synthetic Reagents
  4. Phosphonium/Uronium/Formamidinium - Coupling
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Coupling - Synthetic Reagents
  4. Phosphonium/Uronium/Formamidinium - Coupling
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Peptide Coupling - Peptide Chemistry
  5. Phosphonium/Uronium/Formamidinium - Peptide Coupling

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