VANADIUM GALLIDE 镓化钒, 99% (metals basis)

CAS 12024-15-6 MFCD02091753

化学结构图

12024-15-6
SMILES: [V].[GaH3]

化学属性

Mol. FormulaV3Ga
Mol. Weight222.55
TSCANo
Melting Point1720°
Appearance 四氟化钛为有吸湿性的白色粉末，相对密度2.798，熔点284℃，常压下284℃即升华。易溶于水并分解，不溶于乙醚。在100℃时与硅氯仿反应生成硅氟仿。可与某些胺类及吡啶等形成加合物。
Boiling Point284°C
Density2.798 g/mL at 25 °C(lit.)

别名和识别编码

Chemical NameVANADIUM GALLIDE
Synonym Titanic fluoride 四氟化钛 Titanium fluoride (TiF4), (T-4)- TITANIUM (IV) FLOURIDE Titanium(IV) fluoride 99% Titanium(IV)fluoride,98% VANADIUM-GALLIUM ALLOY CEFUROXIME,FREE ACID GaV3 Titanium(IV)fluoride99% TiF4 Titanium(IV) fluoride Cefuroxin CP2000,BP98 氟化钛(IV) Titanium(IV) tetrafluoride VANADIUM GALLIDE 头孢呋辛酸 V3Ga Titanium tetrafluoride
MDL NumberMFCD02091753
CAS Number12024-15-6
EC Number232-017-6
Chemical Name Translation镓化钒, 99% (metals basis)
Merck Number14,9479
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分类

  • {Chemicalbook} 无机化工产品: 无机盐: Cp钼、钛、钨、钒、锆

相关文献及参考

  • Short: III/13a Title: Metals: Phonon States, Electron States and Fermi Surfaces: Phonon States of Elements. Electron States and Fermi Surfaces of Alloys Author: Dederichs, P.H.; Schober, H.; Sellmyer, D.J. Editor: Hellwege, K.-H.; Olsen, J.L. Source: Landolt-Börnstein, New Series Volume: III/13a Year: 1981 ISBN: 3-540-09774-0 ISBN: 978-3-540-09774-7 Internet Resource: DOI:10.1007/b19988 RefComment: 904 figs., X, 458 pages. Hardcover Abstract: Volume III/13 covers data on phonon and electron states and Fermi surfaces of metals. Both experimental and theoretical results published up to 1980 are included. Metallic elements and compounds, disordered alloys as well as homogeneously strained metallic elements are con-sidered. An appendix presents a compilation of all Bravias lattices, primitive unit cells, reciprocal lattices, and first Brillouin zones.
  • Short: III/13b Title: Metals: Phonon States, Electron States and Fermi Surfaces: Phonon States of Alloys. Electron States and Fermi Surfaces of Strained Elements Author: Fawcett, E.; Griessen, R.; Joss, W.; Kress, W. Editor: Hellwege, K.-H.; Olsen, J.L. Source: Landolt-Börnstein, New Series Volume: III/13b Year: 1983 ISBN: 3-540-10661-8 ISBN: 978-3-540-10661-6 Internet Resource: DOI:10.1007/b19989 RefComment: 703 figs., VIII, 405 pages. Hardcover Abstract: Volume III/13 covers data on phonon and electron states and Fermi surfaces of metals. Both experimental and theoretical results published up to 1980 are included. Metallic elements and compounds, disordered alloys as well as homogeneously strained metallic elements are con-sidered. An appendix presents a compilation of all Bravias lattices, primitive unit cells, reciprocal lattices, and first Brillouin zones.
  • Short: III/19b Title: Magnetic Properties of Metals: Alloys and Compounds of d-Elements with Main Group Elements. Part 1 Author: Booth, J.G.; Wijn, H.P.J.; Zibold, G. Editor: Wijn, H.P.J. Source: Landolt-Börnstein, New S

安全信息

Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Packing GroupIII
UN Number UN 3260 8/PG 2 UN3285
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R25 Toxic if swallowed 吞咽有毒
Hazard Class8
Hazard Codes C
WGK Germany3

其他信息

  • 用途一:用于成膜材料及离子注人掺杂。在微电子工业上用于化学气体沉积，以制作低电阻、高熔点的互连线。
  • 参考质量标准:参考标准 指标名称 指标 四氟化钛(TiF4)/%≥ 99
  • 四氟化钛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 308431000 四氟化钛 Titanium(IV) fluoride 99% 100 GR 2214元 2010/06/21 308430100 四氟化钛 Titanium(IV) fluoride 99% 10 GR 341元 2010/05/25 11540 氟化钛(IV), 98% Titanium(IV) fluoride, 98% 25g 636元
  • Acros Organics:四氟化钛 Titanium(IV) fluoride, 99%(7783-63-3)
  • 上游原料:氢氟酸 --> 四氯化钛
  • 方法一:以四氯化钛和氟化氢为原料制备四氟化钛，将50%的四氯化钛按化学计量比的量装入铂制或铜制的反应器中，滴加氟化氢使其反应，将反应物静置数小时，再徐徐加热，加热至200℃时蒸馏出含氟化氢的氯化氢，再继续升温至284℃以上使四氟化钛升华，经冷却即得到四氟化钛粉末产品，用密封的铜制容器贮存。其反应如下：
  • Alfa Aesar:氟化钛(IV),98% Titanium(IV) fluoride, 98%(7783-63-3)
  • Sigma Aldrich:7783-63-3(sigmaaldrich)
  • Hazard Note:Corrosive
  • 敏感性:Moisture Sensitive
  • MSDS 信息:Titanium tetrafluoride(7783-63-3).msds
  • MOL 文件:7783-63-3.mol

系列性分类

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