(1S,4R)-2-Azabicyclo[2.2.1]Hept-5-En-3-One (1S,4R)-2-氮杂双环[2.2.1]庚-5-烯-3-酮

CAS 130931-83-8 MFCD00211275

化学结构图

130931-83-8
SMILES: O=C1N[C@@H]2C=C[C@H]1C2

化学属性

Mol. FormulaC6H7NO
Mol. Weight109.13
Melting Point94-97 °C(lit.)

别名和识别编码

Chemical Name(1S,4R)-2-Azabicyclo[2.2.1]Hept-5-En-3-One
CAS Number130931-83-8
Alfabeta NameAZABICYCLOHEPTENONE RS14322152..[]()------,
MDL NumberMFCD00211275
PubChem Substance ID24867650
Chemical Name Translation(1S,4R)-2-氮杂双环[2.2.1]庚-5-烯-3-酮
Synonym (1S)-(+)-2-氮杂双环[2.2.1]庚-5-烯-3-酮
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Lactams, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Lactams, Organic Building Blocks

相关文献及参考

  • Evans, C.T. et al. J. Chem. Soc. Perkin Trans. I , 589, (1992)
  • Campbell, J.A. et al. J. Org. Chem. 60 , 4602, (1995)
  • Handa, S. et al. J. Chem. Soc. Perkin Trans. I , 1885, (1994)
  • White, E.L. et al. Biochem. Biophys. Res. Commun. 161 , 393, (1989) 摘要
  • Vince, R. Hua, M. J. Med. Chem. 33 , 17, (1990) 摘要
  • Jung. M.E. Rhee, H. J. Org. Chem. 59 , 4719, (1994)
  • FT-IR 2 (1), 1289:B / Structure Index 1 , 138:B:3

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Lactams - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Lactams - Organic Building Blocks

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