Phenylphosphinic acid 苯基次膦酸

CAS 1779-48-2 MFCD00002131

化学结构图

1779-48-2
SMILES: O=[PH](O)c1ccccc1

化学属性

Mol. FormulaC6H7O2P
Mol. Weight142.09
Melting Point83-85 °C
TSCAYes
Boiling Point180 °C at 760 mmHg
Solubility7.7 G/100 ML (25 ºC)
Appearance 白色晶体，熔点 82-87℃，沸点 180℃，水溶性 7.7g/100mL

别名和识别编码

Chemical NamePhenylphosphinic acid
CAS Number1779-48-2
PubChem Substance ID87563238
EC Number217-217-3
Beilstein Registry Number16,791
MDL NumberMFCD00002131
Synonym Phenylphosphinic acid {LY} Phenylphosphinic acid {} {LY} Phenylphosphinic acid {} {} {LY} Phenylphosphinic acid {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylphosphinic acid {} {} {} {} {} {}
Reaxys-RN2802244
Chemical Name Translation苯基次膦酸
LabNetwork Molecule IDLN00198145
InChIInChI=1S/C6H5O2P/c7-9(8)6-4-2-1-3-5-6/h1-5H/p+1
Canonical SMILESO=P(O)C1=CC=CC=C1
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分类

  • {SNA} Acids, Building Blocks, Chemical Synthesis, Electronic Chemicals, Micro/NanoElectronics, Organic Building Blocks,
  • {SNA} Acids, Building Blocks, Chemical Synthesis, Electronic Chemicals, Materials Science, Micro/NanoElectronics, Organic Building Blocks, Phosphonic/Phosphinic Acids, Phosphorus Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Acids, Building Blocks, Chemical Synthesis, Electronic Chemicals, Materials Science, Micro/NanoElectronics, Organic Building Blocks, Phosphonic/Phosphinic Acids, Phosphorus Compounds
  • {SNA} Acids,

相关文献及参考

  • Beil. 16 ,IV,1033
  • FT-IR 1 (2), 552:B / FT-IR 2 (2), 3347:C / FT-NMR 1 (2), 1684:B / IR-Spectra (3), 1188:B / IR-Spectra (2), 1034:H / NMR-Reference 2 (2), 889:A / RegBook 1 (2), 2285:H / Structure Index 1 , 358:A:1
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of bor

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes C C;Xn C,Xn
RTECSSZ5462500
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger {} {} {} {} {} {} {TCI}
UN Number 3261 UN 3261 8/PG 3 UN3261
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
Packing GroupIII
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1345 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555311

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >625 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 2,56,1950

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >4640 mg/kg
TOXIC EFFECTS :
   Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555311

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:1779-48-2(sigmaaldrich)
  • 图谱信息:苯膦酸(1779-48-2)红外图谱(IR2) 苯膦酸(1779-48-2)核磁图( 13 CNMR) 苯膦酸(1779-48-2)质谱(MS) 苯膦酸(1779-48-2)红外图谱(IR1) 苯膦酸(1779-48-2)Raman光谱 苯膦酸(1779-48-2)核磁图( 1 HNMR)
  • TCI Shanghai:苯膦酸 Phenylphosphinic Acid,>;99.0%(T)(1779-48-2)
  • Alfa Aesar:苯基磷酸,98% Phenylphosphinic acid, 98%(1779-48-2)
  • MSDS 信息:Benzenephosphinic acid(1779-48-2).msds
  • Acros Organics:苯基次膦酸 Phenylphosphinic acid, 99%(1779-48-2)
  • 苯膦酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0025 苯膦酸 Phenylphosphinic Acid 500G 986元 2014/06/02 B0025 苯膦酸 Phenylphosphinic Acid 25G 163元 2010/06/21 130780050 苯膦酸 Phenylphosphinic acid 99% 5 GR 247元
  • MOL 文件:1779-48-2.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonic/Phosphinic Acids - Phosphorus Compounds
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Electronic Chemicals - Micro/NanoElectronics
  4. Electronic Chemicals: Acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonic/Phosphinic Acid Anhydrides - Phosphorus Compounds

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