1-Methyl-3-nitroguanidine 1-甲基-3-硝基胍

CAS 4245-76-5 MFCD00024167

化学结构图

4245-76-5
SMILES: CNC(=N)N[N+](=O)[O-]

化学属性

Mol. FormulaC2H6N4O2
Mol. Weight118.09
Melting Point153-155 °C
Appearance 白色粉末状固体,熔点 153-155℃
Density1.57
Boiling Point220.6 °C at 760 mmHg

别名和识别编码

Chemical Name1-Methyl-3-nitroguanidine
MDL NumberMFCD00024167
PubChem Substance ID87572754
CAS Number4245-76-5
Reaxys-RN5495905
Synonym 1-Methyl-3-nitroguanidine {LY} 1-Methyl-3-nitroguanidine {} {LY} 1-Methyl-3-nitroguanidine {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-3-nitroguanidine {} {} {} {} {} {}
Chemical Name Translation1-甲基-3-硝基胍
Beilstein Registry Number5495905
LabNetwork Molecule IDLN00223704
InChIInChI=1S/C2H6N4O2/c1-4-2(3)5-6(7)8/h1H3,(H3,3,4,5)
Canonical SMILESN=C(N[N+]([O-])=O)NC
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分类

  • Building Blocks, Chemical Synthesis, Guanidines, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Building Blocks, Chemical Synthesis, Guanidines, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Beilstein: 4,II,572

安全信息

RTECSMF4125000
WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P350
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H228 Flammable solid 易燃固体
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes 4.1 F,Xn
GHS Symbol
Personal Protective Equipment dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
UN Number 1325
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S48 Keep wet with ... (appropriate material to be specified by the manufacturer) 用……(生产厂家指定的适当物料)保持湿润;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupII
Hazard Class4.1
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TIHEEC Toxicology and Industrial Health.  (Princeton Scientific Pub. Co.,
   POB 2155, Princeton, NJ 08540)  V.1-    1985-  Volume(issue)/page/year:
   9,457,1993

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 3300 mg/L
REFERENCE :
   GMCRDC Gann Monograph on Cancer Research.  (Plenum Pub. Corp., 233 Spring
   St., New York, NY 10013) No. 11-    1971-  Volume(issue)/page/year:
   27,95,1981

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 6 gm/L/48H
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 48,337,1977

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 1-甲基-3-硝基胍价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0749 1-甲基-3-硝基胍(加约25%水湿润,本品干重分别为约5g和25g) 1-Methyl-3-nitroguanidine (wetted with ca. 25% Water, containing 5g and 25g on a dry weight basis respectively) 5G 182元 2014/06/02 M0749 1-甲基-3-硝基胍(加约25%水湿润,本品干重分别为约5g和25g) 1-Methyl-3-nitroguanidine (wetted with ca. 25% Water, containing 5g and 25g on a dry weight basis respectively) 25G 499元
  • 图谱信息:1-甲基-3-硝基胍(4245-76-5)质谱(MS) 1-甲基-3-硝基胍(4245-76-5)红外图谱(IR2) 1-甲基-3-硝基胍(4245-76-5)Raman光谱 1-甲基-3-硝基胍(4245-76-5)核磁图( 13 CNMR) 1-甲基-3-硝基胍(4245-76-5)红外图谱(IR1)
  • Sigma Aldrich:4245-76-5(sigmaaldrich)
  • TCI Shanghai:N-甲基-N'-硝基胍(加约25%水湿润,本品干重分别为约5g和25g) N-Methyl-N'-nitroguanidine (wetted with ca. 25% Water, containing 5g and 25g on a dry weight basis respectively),>;98.0%(T)(4245-76-5)
  • MOL 文件:4245-76-5.mol
  • 下游产品:1-甲基-3-硝基-1-亚硝基胍
  • 用途一:用作农药、医药中间体

系列性分类


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