Triphenylantimony 三苯基锑

CAS 603-36-1 MFCD00003000

化学结构图

603-36-1
SMILES: c1ccc([Sb](c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC18H15Sb
Mol. Weight353.07
Boiling Point377 °C at 760 mmHg
Melting Point52-54 °C
Flash Point109°(228°F)
TSCAYes
Density1.43
Solubility不溶

别名和识别编码

Chemical NameTriphenylantimony
Synonym Triphenylantimony {LY} Triphenylantimony {} {LY} Triphenylantimony {} {} {LY} Triphenylantimony {} {} {} {LY} Triphenylantimony {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylantimony {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number603-36-1
PubChem Substance ID11777
EC Number210-037-6
Beilstein Registry Number16,891
MDL NumberMFCD00003000
Reaxys-RN3608108
Chemical Name Translation三苯基锑
Wiswesser Line NotationR-SB-R&R
LabNetwork Molecule IDLN00222073
InChIInChI=1S/3C6H5.Sb/c3*1-2-4-6-5-3-1;/h3*1-5H;
Canonical SMILES[Sb](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
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分类

  • {SA} Antimony, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
  • {uni_hamburg} no charge; metal-organic; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Antimony, Catalysis and Inorganic Chemistry, Chemical Synthesis
  • {SNA} Antimony, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学

相关文献及参考

  • Beilstein:16,891
  • Short: III/20c
  • Short: III/35C4
  • Short: III/5b
  • {} {

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H332 Harmful if inhaled 吸入有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn;N Xn,N
RTECSWJ1400000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P301+P310+P330
  • P301+P312
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number UN 3467 6.1/PG 3 3467
Safety Statements
Risk Statements
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 183 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1280,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,229,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 168 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-74-78,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 650 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-74-78,1974

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • 不溶于水，微溶于醇，溶于大多数有机溶剂，二氧六环溶解度：1G/10ML 。
  • TCI Shanghai:三苯锑 Triphenylantimony,>;95.0%(T)(603-36-1)
  • 图谱信息:三苯基锑(603-36-1)红外图谱(IR1) 三苯基锑(603-36-1)核磁图( 13 CNMR) 三苯基锑(603-36-1)核磁图( 1 HNMR) 三苯基锑(603-36-1)红外图谱(IR2) 三苯基锑(603-36-1)质谱(MS)
  • 急性毒性:口服-大鼠 LD50: 183 毫克/公斤; 口服-小鼠 LD50: 650 毫克/公斤
  • 海关编码:29310095
  • 三苯基锑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0476 三苯锑 Triphenylantimony 25G 327元
  • 毒性分级:高毒
  • 职业标准:TWA 0.5 毫克 (锑)/立方米
  • 可燃性危险特性:受热在空气中自燃; 燃烧产生有毒锑化物烟雾
  • MOL 文件:603-36-1.mol
  • 类别:自燃物品
  • 灭火剂:干粉,泡沫,沙土,二氧化碳
  • 下游产品:(6R,7R)-7-[[(2-氨基-4-噻唑基)-[(1-羧基-1-甲基乙氧基)亚氨基]乙酰基]氨基]-2-羧基-8-氧代-5-硫杂-1-氮杂双环[4.2.0]辛-2-烯-3-甲基吡啶鎓内盐 --> 三氯蔗糖 --> 去氧氟尿苷 --> 丙泊酚
  • Sigma Aldrich:603-36-1(sigmaaldrich)
  • TSCA:Yes
  • 储运特性:库房通风低温干燥; 与食品原料, BF3分开存放
  • MSDS 信息:Triphenylantimony(603-36-1).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Antimony - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Antimony - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organocopper - Organometallic Reagents
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Antimony - CVD and ALD Precursors by Metal
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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