Diazoaminobenzene 重氮氨基苯

CAS 136-35-6 MFCD00003021

化学结构图

136-35-6
SMILES: C1=CC=CC=C1/N=N/NC1C=CC=CC=1

化学属性

Mol. FormulaC12 H11 N3
Mol. Weight197.236
Density1.422
Melting Point96-100
Solubility不溶于水，易溶于苯、热醇、醚。
Boiling Point-
Flash Point-

别名和识别编码

Chemical NameDiazoaminobenzene
CAS Number136-35-6
Alfabeta NameDIPHENYLTRIAZENE E1131()----,
MDL Number-
Synonym 1,3-Diphenyltriazene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number205-240-1
Beilstein Registry Number957560
Chemical Name Translation重氮氨基苯
Reaxys-RN957560
Merck Number2998
Wiswesser Line NotationRNUNMR
Canonical SMILES-
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: III/10a Title: Structure Data of Organic Crystals: C ... C 15 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10a Year: 1985 ISBN: 3-540-07834-7 ISBN: 978-3-540-07834-0 Internet Resource: DOI:10.1007/b19984 RefComment: XXII, 634 pages. Hardcover Abstract: The volume includes an alphabetical index of all substances and a separate "ring index" with all cyclic compounds.
  • Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esi

安全信息

Warnings IRRITANT 危化品目录(2015) 危险化学品
Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P332+P313
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P302+P350
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSXY2625000
UN Number
Hazard statements
  • H242 Heating may cause a fire 加热可能会引起火灾
Hazard Class4.1
Hazard Codes 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 30 gm/kg/46W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   2,290,1948

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1480 mg/kg/59D-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   29,209,1935

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 300 ng/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9(Suppl
   9),1,1987

Storage condition N/A N/A℃ No Data Available

其他信息

  • 灭火剂:水、干砂、二氧化碳、泡沫、1211灭火剂
  • 方法一:由苯胺与亚硝酸钠作用，再与苯胺缩合而得。
  • MSDS 信息:重氮氨基苯(136-35-6).msds
  • 外观性质:金黄色结晶。
  • 类别:易燃固体
  • 爆炸物危险特性:与氧化剂混合可爆
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
  • 图谱信息:重氮胺基苯(136-35-6)红外图谱(IR1) 重氮胺基苯(136-35-6)红外图谱(IR2) 重氮胺基苯(136-35-6)核磁图( 13 CNMR) 重氮胺基苯(136-35-6)质谱(MS)
  • 下游产品:4-氨基联苯氨盐酸盐
  • 急性毒性:参考值: 腹腔-小鼠LD50: 200 毫克/公斤
  • 重氮胺基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0136 重氮氨基苯 Diazoaminobenzene 500G 11020元 2014/06/02 D0136 重氮氨基苯 Diazoaminobenzene 25G 1300元
  • MOL 文件:136-35-6.mol
  • Sigma Aldrich:136-35-6(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 用途一:有机合成中间体。用于制备对氨基偶氮苯，向合成锅中加入苯胺和亚硝酸钠溶液，在30-40℃、2.5-3h内搅拌下加入30%盐酸，升温至50-55℃，重氮氨基苯经转位生成对氨基偶氮苯：作为染料中间体，用于合成偶氮染料、分散染料、噁嗪染料。重氮氨基苯还用作起泡剂、硫化剂和引发剂。

系列性分类

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