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• 试剂商城
• 直接询价

分类

• {SNA} Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
• {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ester; 1fragment

产品应用

• 该品在三氯化铝存在下加热至130℃，重排生成4-羟基二苯酮，用作有机合成中间体，用于生产医药等产品。

相关文献及参考

• Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
• Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
• Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shif

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1225 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKKZAJ Yakugaku Zasshi.  Journal of Pharmacy.  (Nippon Yakugakkai, 2-12-15
   Shibuya, Shibuya-ku, Tokyo 150, Japan)  No.1-    1881-
   Volume(issue)/page/year: 89,1179,1969

其他信息

• 上游原料:苯甲酰氯
• 下游产品:4-羟基-二苯甲酮
• Acros Organics:苯甲酸苯酯 Phenyl benzoate, 99%(93-99-2)
• TCI Shanghai:苯甲酸苯酯 Phenyl Benzoate,>;99.0%(GC)(93-99-2)
• 苯甲酸苯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0075 苯甲酸苯酯 Phenyl Benzoate 25G 144元 2014/06/02 B0075 苯甲酸苯酯 Phenyl Benzoate 500G 1320元 2010/06/21 162061000 苯甲酸苯酯 Phenyl benzoate 99% 100 GR 424元
• 用途二:用于羟基化二苯酮的合成
• Alfa Aesar:苯甲酸苯酯,99% Phenyl benzoate, 99%(93-99-2)
• 图谱信息:苯甲酸苯酯(93-99-2)核磁图( 1 HNMR) 苯甲酸苯酯(93-99-2)质谱(MS) 苯甲酸苯酯(93-99-2)核磁图( 13 CNMR) 苯甲酸苯酯(93-99-2)红外图谱(IR2) 苯甲酸苯酯(93-99-2)Raman光谱 苯甲酸苯酯(93-99-2)红外图谱(IR1)
• 方法一:由苯甲酰氯与苯酚反应而得。将苯酚溶解于吡啶中，滴加苯甲酰氯，控制温度不超过50℃，加毕，于120℃反应30min。冷却后加水析出结晶，过滤，洗涤干燥即得苯甲酸苯酯。收率93%。上述酰化反应也可将苯酚钠盐溶液与苯甲酰氯在室温反应0.5h，经过滤、水洗即得苯甲酸苯酯，精制进可采用乙醇重结晶，收率75-80%。
• 易溶于热乙醇，微溶于冷乙醇和乙醚，不溶于水,有草叶油味。
• Sigma Aldrich:93-99-2(sigmaaldrich)
• 用途三:该品在三氯化铝存在下加热至130℃，重排生成4-羟基二苯酮，用作有机合成中间体，用于生产医药等产品。
• MOL 文件:93-99-2.mol
• 用途一:用于制药及有机合成