Furfurylamine 2-呋喃甲胺

CAS 617-89-0 MFCD00003258

化学结构图

617-89-0
SMILES: NCC1CCCO1

化学属性

Mol. FormulaC5H7NO
Mol. Weight97.12
Refractive index1.4890 to 1.4910
Boiling Point
Density1.099
Melting PointN/A
Flash Point46.67°C
TSCAYes
Vapor Density3.35 (vs air)
Vapor Pressure4 mmHg ( 20 °C)
Solubility可溶
Stability对空气敏感

别名和识别编码

Chemical NameFurfurylamine
CAS Number617-89-0
Synonym 2-Furfurylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87569891
EC Number210-536-9
Beilstein Registry Number1614
MDL NumberMFCD00003258
Reaxys-RN1614
Chemical Name Translation2-呋喃甲胺
Wiswesser Line NotationT5OJ B1Z
LabNetwork Molecule IDLN00008195
InChIInChI=1S/C5H7NO/c6-4-5-2-1-3-7-5/h1-3H,4,6H2
Canonical SMILESNCC1=CC=CO1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • Heterocycles
  • Amines
  • {uni_hamburg} no charge; oxygen heterocycle; aromatic; 5ring; ether; 1fragment
  • Miscellaneous Reagents
  • {SNA} Building Blocks, C4 to C7, Chemical Synthesis, Furans, Heterocyclic Building Blocks

产品应用

  • 用作腐蚀抑制剂、助焊剂。用于有机合成。糠胺与2,4-二氯-5-氨磺酰基苯甲酸缩合可得强效利尿药速尿。速尿作利尿作用强而快，是治疗亚重水肿所必需的药物，糠胺也用作抗腐蚀剂。

相关文献及参考

  • Beilstein:18,584
  • Short: II/14a
  • Marahiel, M., et al.: Chem. Biol. 4, 561 (1997),
  • Short: II/2
  • Faber, K., et al.: Pure Appl. Chem., 69, 1613 (1997),
  • Short: II/24B
  • Mah, R., et al.: Appl. Microbiol., 15, 866 (1967),

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 3 C
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302+H312
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSLU9275000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2526
Risk Statements
  • R10 Flammable 易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R23/24 Toxic by inhalation and in contact with skin 吸入及皮肤接触都有毒
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Storage condition +4°C 2-8°C 4 4℃ Keep Cold {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Packing GroupIII
Hazard Class3/8
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

Restrict 危险品

其他信息

  • 上游原料:不锈钢反应釜
  • 急性毒性:腹腔- 小鼠 LDL0: 200 毫克/ 公斤
  • 类别:较易燃液体
  • 海关编码:29321900
  • 图谱信息:2-呋喃甲胺(617-89-0)红外图谱(IR1)
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • Alfa Aesar:糠胺,99% Furfurylamine, 99%(617-89-0)
  • TCI Shanghai:糠胺 Furfurylamine,>;98.0%(GC)(617-89-0)
  • 毒性分级:中
  • MOL 文件:617-89-0.mol
  • 2-呋喃甲胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 AF2000902 糠胺≥99％ 100g 264元 2011/08/23 80065980 糠胺;2-呋喃甲胺;麸胺 100ml 280元 2011/04/16 F0091 糠胺 Furfurylamine 25ML 109元
  • 外观性质:无色至淡黄色液体。
  • 溶于水，溶于乙醇、乙醚，引燃温度(℃)： 490.5 。在空气中吸收二氧化碳变质。
  • 方法一:由糠醛氨化，催化氢化而得。将糠醛，镍投入不锈钢反应釜，再加入经氨饱和的甲醇。通氮置换釜内空气，然后通氢，在45-60℃，8.8MPa下搅拌吸氢4h，至釜压不变为终点。将反应物过滤，滤液回收甲醇至尽，减压蒸馏，收集45-67℃（0-5.32kPa）馏分，即为糠胺，收率约40%。
  • MSDS 信息:糠胺(617-89-0).msds
  • Sigma Aldrich:617-89-0(sigmaaldrich)
  • 用途三:用作腐蚀抑制剂、助焊剂。用于有机合成。糠胺与2,4-二氯-5-氨磺酰基苯甲酸缩合可得强效利尿药速尿。速尿作利尿作用强而快，是治疗亚重水肿所必需的药物，糠胺也用作抗腐蚀剂。
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
  • Acros Organics:2-呋喃甲胺 Furfurylamine, 99+%(617-89-0)
  • 蒸气密度:3.35 (vs air)
  • 下游产品:呋噻米
  • 用途一:用于制药及有机合成
  • 蒸气压:4 mm Hg ( 20 °C)
  • 用途二:用于有机合成。糠胺与2,4-二氯-5-氨磺酰基苯甲酸缩合可得强效利尿药速尿。速尿作利尿作用强而快，是治疗亚重水肿所必需的药物，糠胺也用作抗腐蚀剂。
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • Hazard Note:Harmful/Corrosive/Flammable

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Coumarins 香豆素
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Furans 呋喃
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. F - Alphabetic
  5. FM - FZ - F
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Furans 呋喃
  5. C4 to C7 - Furans

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