Cholesteryl Chloroformate 胆固醇甲酰氯

CAS 7144-08-3 MFCD00003633

化学结构图

7144-08-3
SMILES: CC(C)CCCC(C)C1CCC2C3CC=C4CC(OC(=O)Cl)CCC4(C)C3CCC12C

化学属性

Mol. FormulaC28H45ClO2
Mol. Weight449.12
Melting Point115-117°C
TSCAYes
SolubilitySoluble in water (reacts).
Density1.05
Stability对湿度敏感
Boiling Point504 °C at 760 mmHg

别名和识别编码

Chemical NameCholesteryl Chloroformate
MDL NumberMFCD00003633
CAS Number7144-08-3
PubChem Substance ID111262
Beilstein Registry Number3223154
EC Number230-447-9
Synonym Cholesteryl chloroformate {LY} Cholesteryl chloroformate {} {LY} Cholesteryl chloroformate {} {} {LY} Cholesteryl chloroformate {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cholesteryl chloroformate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cholesteryl chlo
Reaxys-RN3223154
Chemical Name Translation胆固醇甲酰氯
InChIKeyQNEPTKZEXBPDLF-JDTILAPWSA-N
LabNetwork Molecule IDLN01741005
InChIInChI=1S/C28H45ClO2/c1-18(2)7-6-8-19(3)23-11-12-24-22-10-9-20-17-21(31-26(29)30)13-15-27(20,4)25(22)14-16-28(23,24)5/h9,18-19,21-25H,6-8,10-17H2,1-5H3/t19-,21+,22+,23-,24+,25+,27+,28-/m1/s1
Canonical SMILESCC(C)CCC[C@@H](C)[C@H]1CC[C@@]2([H])[C@]3([H])CC=C4C[C@@H](OC(Cl)=O)CC[C@]4(C)[C@@]3([H])CC[C@]12C
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Cholesteric, Complex Molecules, Liquid Crystals, Materials Science, Organic and Printed Electronics
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Cholesteric, Complex Molecules, Liquid Crystals, Organic and Printed Electronics, 材料科学

产品应用

  • 引发剂。

相关文献及参考

  • Beilstein: 6,IV,4010
  • Has been used as a means of introducing a bulky, organic-soluble group for the isolation of small quantities of primary and secondary amines from aqueous solution: Can. J. Chem., 31, 688 (1953).

安全信息

GHS Symbol
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
WGK Germany3
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupIII
UN Number UN 3261 8/PG 2 UN3261 3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive O-6°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes C
Hazard Class8

其他信息

  • 比旋光度:-28 ° (c=2, CHCl3 27 °C)
  • 用途一:引发剂。
  • TCI Shanghai:胆固醇氯甲酸酯 Cholesterol Chloroformate,>;98.0%(T)(7144-08-3)
  • MSDS 信息:Cholesteryl chloroformate(7144-08-3).msds
  • 胆固醇甲酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C0694 氯甲酸胆固醇酯 Cholesterol Chloroformate 25G 553元 2010/06/21 110231000 胆固醇甲酰氯 Cholesteryl chloroformate 97% 100 GR 1405元 2010/06/21 110230250 胆固醇甲酰氯 Cholesteryl chloroformate 97% 25 GR 564元
  • 胆固醇甲酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0694 氯甲酸胆固醇酯 Cholesterol Chloroformate 25G 500元 2010/06/21 110231000 胆固醇甲酰氯 Cholesteryl chloroformate 97% 100 GR 1405元 2010/06/21 110230250 胆固醇甲酰氯 Cholesteryl chloroformate 97% 25 GR 564元
  • MOL 文件:7144-08-3.mol
  • Alfa Aesar:胆固醇氯甲酸酯,98% Cholesteryl chloroformate, 98%(7144-08-3)
  • F:10-21
  • Sigma Aldrich:7144-08-3(sigmaaldrich)
  • 海关编码:29159020
  • 敏感性:Moisture Sensitive
  • Acros Organics:氯甲酸胆甾醇酯 Cholesteryl chloroformate, 97%(7144-08-3)
  • 图谱信息:胆固醇甲酰氯(7144-08-3)红外图谱(IR2) 胆固醇甲酰氯(7144-08-3)红外图谱(IR1) 胆固醇甲酰氯(7144-08-3)核磁图( 1 HNMR) 胆固醇甲酰氯(7144-08-3)核磁图( 13 CNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Complex Molecules - Chiral Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Complex Molecules - Chiral Building Blocks
  1. Materials Science 材料科学
  2. Liquid Crystals

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