2,4,6-Trinitrotoluene 2,4,6-Trinitrotoluene

CAS 118-96-7 MFCD00041875

化学结构图

118-96-7
SMILES: Cc1c([N+](=O)[O-])cc([N+](=O)[O-])cc1[N+](=O)[O-]

化学属性

Mol. FormulaC7H5N3O6
Mol. Weight227.15
Flash Point2 °C
Melting Point81.8°C
Density0.7915
Boiling Point280°C
Solubility不溶于水，微溶于乙醇，溶于苯、芳烃、丙酮。

别名和识别编码

Chemical Name- min 30wt% water Solution
Synonym 1-Methyl-2,4,6-trinitrobenzene 1-甲基-2,4,6-三硝基苯 2 2,4,6-TNT 2,4,6-TRINITROTOLUENE 2,4,6-Trinitro-toluol 2,4,6-Trinitrotolueen 2,4,6-Trinitrotoluene 2,4,6-Trinitrotoluol 2,4,6-trinitro-toluen 2,4,6-trinitro-toluene 2,4,6-trinitrotoluene 2,4,6-三硝基甲苯 2-Methyl-1,3,5-Trinitrobenzene 2-Methyl-1,3,5-trinitrobenzene 2-Methyl-1,3,5-trinitrobenzol 2-methyl-1,3,5-trinitro-Benzene 2-methyl-1,3,5-trinitro-benzen 2-methyl-1,3,5-trinitro-benzene 2-甲基-1 2-甲基-1,3,5-三硝基苯 2，4，6-三硝基甲苯，梯恩梯 3 4 5-三硝基苯，1-甲基-2 6-三硝基甲苯 6-三硝基苯，梯恩梯 sym-Trinitrotoluol sym-trinitrotoluene Benzene, 2-methyl-1,3,5-trinitro- {Chemic
CAS Number118-96-7
Chemical Name Translation2,4,6-Trinitrotoluene
EC Number204-289-6
MDL NumberMFCD00041875
Wiswesser Line NotationWNR B1 CNW ENW
PubChem Substance ID8376
InChIInChI=1S/C7H5N3O6/c1-4-6(9(13)14)2-5(8(11)12)3-7(4)10(15)16/h2-3H,1H3
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 用于制造染料、医药、炸药，也作试剂等。

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31a Year: 1993 Keyword: NQR ISBN: 3-540-55146-8 ISBN: 978-3-540-55146-1 Internet Resource: DOI:10.1007/b43999 RefComment: VIII, 437 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data published there could be completed or improved by new studies. In total there are 2500 substances in volume III/31, showing the scope and significance of nuclear quadrupole resonanc

安全信息

Hazard Codes E,T,N,Xn,F,B
Hazard Class1.1D
Storage condition 2-8°C
UN Number 0209
Safety Statements
  • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R1 Explosive when dry 干燥时易爆
  • R2 Risk of explosion by shock, friction, fire or other sources of ignition 遇到震动、摩擦、火焰或者其它引燃物有爆炸危险
  • R11 Highly flammable 非常易燃
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R51/53
  • R36 Irritating to eyes 刺激眼睛
  • R33 Danger of cumulative effects 有累积作用的危险
Warnings 危化品目录(2015) 危险化学品
RTECSXU0175000 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 795 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 9,565,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 660 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 9,565,1982

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 28 gm/kg
TOXIC EFFECTS :
   Behavioral - hallucinations, distorted perceptions
   Lungs, Thorax, or Respiration - cyanosis
   Gastrointestinal - other changes
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,610,1969

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - hypermotility, diarrhea
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   MRCSAB Special Report Series--Medical Research Council (

TYPE OF TEST            : Body fluid assay
TEST SYSTEM             : Rodent - rat Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 262,167,1991

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 40 mg/L
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   20,103,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A080-146

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 5376 mg/kg
SEX/DURATION            : male 28 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 9,565,1982

Hazard statements
  • H201 Explosive; mass explosion hazard 爆炸品；大规模爆炸危险。
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H331 Toxic if inhaled 吸入中毒
  • H350 May cause cancer 可能致癌
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P230 Keep wetted with … 保持湿润
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P250 Do not subject to grinding/shock/…/friction. 不要受研磨/冲击/....../摩擦。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P312
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P307+P311
  • P308+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P380
  • P372 Explosion risk in case of fire. 在火中有灾爆炸的危险。
  • P373 DO NOT fight fire when fire reaches explosives. 火烧到爆炸物时，切勿救火。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P401 Store… 存储
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 毒性分级:中毒
  • 灭火剂:水
  • 爆炸物危险特性:高热、震动、撞击、摩擦可爆
  • 可燃性危险特性:燃烧产生有毒氮氧化物烟雾
  • 刺激数据:皮肤- 兔子 500 毫克/ 24小时 轻度
  • 职业标准:TWA 0.5 毫克/ 立方米; STEL 2.5 毫克/ 立方米
  • 用途一:广泛用于装填各种炮弹、航空炸弹、火箭弹、导弹、水雷、鱼雷、手榴弹及爆破器材
  • MSDS 信息:2,4,6-三硝基甲苯(118-96-7).msds
  • Sigma Aldrich:118-96-7(sigmaaldrich)
  • 外观性质:白色或黄色针状结晶，无臭，有吸湿性。
  • 急性毒性:口服- 大鼠 LD50: 607 毫克/ 公斤; 口服- 小鼠 LD50: 660 毫克/ 公斤
  • MOL 文件:118-96-7.mol
  • 无臭，有吸湿性。不溶于水，微溶于乙醇，溶于苯、芳烃、丙酮。
  • 用途二:用于制造染料、医药、炸药，也作试剂等。
  • 储运特性:轻装轻放; 库房通风、远离明火、高温、阳光、与氧化剂、碱分开存放
  • 类别:爆炸物品

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TP - TZ - T

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