Tris(Trimethylsilyl)Amine 三(三甲基硅)胺

CAS 1586-73-8 MFCD00047990

化学结构图

1586-73-8
SMILES: C[Si](C)(C)N([Si](C)(C)C)[Si](C)(C)C

化学属性

Mol. FormulaC9H27NSi3
Mol. Weight233.57
Boiling Point72 °C/10 mmHg(lit.)
Melting Point67-69 °C(lit.)
Density0.863
Flash Point67°(152°F)
TSCAYes
Refractive index1.4550

别名和识别编码

Chemical NameTris(Trimethylsilyl)Amine
Synonym Tris(trimethylsilyl)amine {LY} Tris(trimethylsilyl)amine {} {LY} Tris(trimethylsilyl)amine {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(trimethylsilyl)amine {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00047990
CAS Number1586-73-8
Beilstein Registry Number1851880
EC Number216-445-0
PubChem Substance ID74110
Chemical Name Translation三(三甲基硅)胺
InChIKeyPEGHITPVRNZWSI-UHFFFAOYSA-N
LabNetwork Molecule IDLN02001988
InChIInChI=1S/C9H27NSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3
Canonical SMILESN([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C
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分类

  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Others
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Other Organosilicon

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive

安全信息

GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
WGK Germany3
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
Packing GroupIII
UN Number UN3259 UN 3259 8/PG 3
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition 2-8°C, sealed storage, away from moisture and light {LY} 2-8°C, sealed storage, away from moisture and light {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
Hazard Codes C
Hazard Class8

其他信息

  • Alfa Aesar:九甲基三硅氮烷,97% Nonamethyltrisilazane, 97%(1586-73-8)
  • Acros Organics:三（三甲基硅）胺 Tris(trimethylsilyl)amine, 99%(1586-73-8)
  • Sigma Aldrich:1586-73-8(sigmaaldrich)
  • 三(三甲基硅)胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 378770050 三(三甲基硅)胺 Tris(trimethylsilyl)amine 99% 5 GR 305元 2010/06/21 378770250 三(三甲基硅)胺 Tris(trimethylsilyl)amine 99% 25 GR 977元 2010/05/25 B23102 九甲基三硅氮烷, 97% Nonamethyltrisilazane, 97% 5g 326元
  • MOL 文件:1586-73-8.mol
  • F:10-21
  • 敏感性:Moisture Sensitive
  • TSCA:Yes

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. I - Alphabetic
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organolithium 有机锂
  4. Others Organosilicon 其他有机硅

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