Tetrakis[(S)-N-(P-Dodecylphenylsulfonyl)Prolinato]Dirhodium(Ii) 四[(S)-N-(对十二烷基苯磺酰)脯氨酸]二铑(II)

CAS 179162-34-6 MFCD00802611

化学结构图

179162-34-6
SMILES:

化学属性

Melting Point195-200 °C (lit.)

别名和识别编码

Synonym Rh2(S-DOSP)4 四[1-[[4-烷基(C11-C13)苯基]磺酰基]-(2S)-吡咯烷羧酸酯]二铑(II)
MDL NumberMFCD00802611
Chemical NameTetrakis[(S)-N-(P-Dodecylphenylsulfonyl)Prolinato]Dirhodium(Ii)
Chemical Name Translation四[(S)-N-(对十二烷基苯磺酰)脯氨酸]二铑(II)
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分类

  • {SNA} Asymmetric Synthesis, Aziridination/Cyclopropanation, C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents
  • {SNA} Asymmetric Synthesis, Aziridination/Cyclopropanation, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Aziridination/Cyclopropanation - Chiral Catalysts, Ligands, and Reagents

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