CAS 93-46-9 MFCD00053487-N,N’-Di-2-Naphthyl-1,4-Phenylenediamine N,N’-二-2-萘基-1,4-苯二胺 -LabNovo

N,N’-Di-2-Naphthyl-1,4-Phenylenediamine N,N’-二-2-萘基-1,4-苯二胺

CAS 93-46-9 MFCD00053487

化学结构图

SMILES: c1ccc2cc(Nc3ccc(Nc4ccc5ccccc5c4)cc3)ccc2c1

化学属性

Mol. Formula	C26H20N2
Mol. Weight	360
Melting Point	225-229 ºC
Boiling Point	232-134 ºC (DEC.)
Density	1.25
Solubility	<0.1 G/100 ML AT 19 ºC
Appearance	浅灰白色粉末,溶于热苯胺、苯、乙醇、丙酮、氯仿、二硫化碳、乙酸乙酯等，不溶于水。

别名和识别编码

Chemical Name	N,N’-Di-2-Naphthyl-1,4-Phenylenediamine
MDL Number	MFCD00053487
CAS Number	93-46-9
Synonym	AgeRite W 1,4-Benzenediamine, N,N'-bis2-naphthyl 1,4-Bis(2-naphthylamino)benzene {hazar Dwu-beta-naftylo-p-fenylodwuamina acetodipp {Chemica Di-beta-naphthyl-p-phenyldiamine N,N'-Bis(2-naphthyl)-p-phenylenediamine; Di-beta-naphthyl-p-phenylenediamine; DBNPD di-beta-naphthyl-p-phenylenediamine N,N'-di-2-naphthyl-p-phenylenediamine N,N'-Di-beta-naphthyl-p-phenylenediamine 1,4-Benzenediamine, N,N'-di-2-naphthalenyl- 对亚苯基二-2-萘胺 N,N'-二(beta-萘基)对苯二胺 N,N'-Di-2-naphthyl-p-phenylenediamine Di-beta-naphthyl-p-phenylenediamine 2-Naphthyl-p-phenylenediamine N,N'-二-2-萘對苯二胺 4-Benzenediamine,N,N’-di-2-naphthalenyl-1 N,N'-DI-2-NAPHTHYL-1,4-PHENYLENEDIAMINE DBNPD DI-B-NAPHTHYL-P-PHENYLENE DIAMINE 橡胶防老剂 DNP N,N’-二(2-萘基)-1,4-苯二胺 ageritewhite sym-Di-beta-naphthyl-p-phenylenediamine AgeRite White Antigene F N,N'-二(β-萘基)对苯二 N,N'-Bis(2-naphthyl)-p-phenylenediamine Nonox CL N,N-DI-2-NAPHTHYL-P-PHENYLENEDIAMINE 防老剂DNPD Tisperse MB-2X N,N'-Bis-(2-naftyl)-p-fenylendiamin N,N'-二-2-萘基-1,4-对苯二胺 Dnpda N,N'-Dinaphthyl-p-phenylen-diamin DNPD N,Nˊ-二-2-萘基对苯二胺防老剂DNP 防老剂 DNPD Aceto DIPP Ageri-tewhite N,N’-二(2-萘基)对苯二胺橡胶防老剂 DNP 对亚苯基二-2-萘胺 N,N'-二(β-萘基)对苯二胺 N,N'-二(2-萘基)对苯二胺 N,N'-二(2-萘基)-1,4-苯二胺 N,N'-DI-2-NAPHTHYL-P-PHENYLENEDIAMINE N,N`-二(Β-萘基)对苯二胺 {Chemicalbo
EC Number	202-249-2
Reaxys-RN	2224419
PubChem Substance ID	87567433
Chemical Name Translation	N,N’-二-2-萘基-1,4-苯二胺
Wiswesser Line Notation	L66J CMR DM- CL66J
Beilstein Registry Number	2224419
LabNetwork Molecule ID	LN00192631
InChI	InChI=1S/C26H20N2/c1-3-7-21-17-25(11-9-19(21)5-1)27-23-13-15-24(16-14-23)28-26-12-10-20-6-2-4-8-22(20)18-26/h1-18,27-28H

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安全信息

RTECSST2100000

Signal word Warning

Hazard statements

H303 May be harmfully swallowed 吞食可能有害

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352+P333+P313+P362+P364
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P332+P313
P333+P313
P337+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....

GHS Symbol

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 31 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 4500 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - other degenerative changes
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 5,311,1952

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Liver - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 31(2),25,1966

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 500 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 241,175,1990

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19(Suppl 21),2,1992

TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MDMIAZ Medycyna Doswiadczalna i Mikrobiologia.  For English translation, see
   EXMMAV.  (Ars Polona, POB 1001, 00-068 Warsaw 1, Poland)  V.1-    1949-
   Volume(issue)/page/year: 31,11,1979

其他信息

方法一:由对苯二胺与β-萘酚缩合而得。将对苯二胺和β-萘酚加入高压釜中，于260-265℃进行缩合反应。反应结束后，将反应产物加入酒精中回流，冷却，过滤，再用乙醇洗涤，干燥，粉碎即得成品。原料消耗(kg/t)对苯二胺 330β-萘酚 1100
用途一:防老剂DNP是广泛用于铜、锰等有害金属抑制和耐热老化抗氧剂对噻唑类促进剂有明显的活化作用。适用于电缆、弹性胶等工业橡胶制品及褐色或暗色乳胶制品中。
Sigma Aldrich:93-46-9(sigmaaldrich)
用途三:主要用作橡胶、乳胶和塑料的抗氧剂。防老剂DNP既是链断裂抑制剂，又是金属络合剂，有优良的耐热老化、耐天然老化和抗铜、锰等有害金属的作用。在丁苯胶中有防紫外光的功能。对胶乳没有不安定作用，也没有使粘度增加的缺点。对噻唑类促进剂有明显的活化作用。适于掺加在天然胶，合成胶及其胶乳制品中。用于制造轮胎帘子线、电缆、弹性胶带及其他工业橡胶制品、胶乳制品（如医疗用品、橡皮膏）等。该品在胺类防老剂中是污染性最小的品种之一，但仍有遇光或遇氧化剂变红的缺点。防老剂DNP的用量为0.2-1份，超过2份会引起喷霜。该品可单独使用，也可与其他防老剂，如防老剂MB、防老剂DOD、防老剂RD等并用。与防老剂124并用特别适于泡沫胶乳制品。防老剂DNP可用作ABS、聚甲醛和聚酰胺类工程塑料的耐热防老剂，用量分别为0.5、0.5和0.3份。亦可用于氯化聚醚，用量1份。在氯化聚醚中与1份紫外线吸收剂UV-9并用，还可以起耐候作用。该品是胺类防老剂中毒性较小的品种。
图谱信息:N,N'-二(2-萘基)对苯二胺(93-46-9)红外图谱(IR2) N,N'-二(2-萘基)对苯二胺(93-46-9)质谱(MS) N,N'-二(2-萘基)对苯二胺(93-46-9)核磁图( 1 HNMR) N,N'-二(2-萘基)对苯二胺(93-46-9)红外图谱(IR1) N,N'-二(2-萘基)对苯二胺(93-46-9)核磁图( 13 CNMR)
MOL 文件:93-46-9.mol
下游产品:抗氧剂
N,N'-二(2-萘基)对苯二胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D0812 N,N'-二-2-萘基-1,4-苯二胺 N,N'-Di-2-naphthyl-1,4-phenylenediamine 500G 1830元 2014/06/02 D0812 N,N'-二-2-萘基-1,4-苯二胺 N,N'-Di-2-naphthyl-1,4-phenylenediamine 25G 277元
上游原料:a-萘酚 --> 对苯二胺
MSDS 信息:Di-beta-naphthyl-p-phenylenediamine(93-46-9).msds
TCI Shanghai:N,N'-二(β-萘基)对苯二胺 N,N'-Di-2-naphthyl-1,4-phenylenediamine,>;96.0%(N)(93-46-9)
用途二:是天然橡胶和合成橡胶的通用型防老剂

N,N’-Di-2-Naphthyl-1,4-Phenylenediamine N,N’-二-2-萘基-1,4-苯二胺

CAS 93-46-9 MFCD00053487

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化学结构图

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