Binapacryl 乐杀螨

CAS 485-31-4 MFCD00055425

化学结构图

485-31-4
SMILES: CCC(C)c1cc([N+](=O)[O-])cc([N+](=O)[O-])c1OC(=O)C=C(C)C

化学属性

Mol. FormulaC15H18N2O6
Mol. Weight322.35
Solubility不溶于水，溶于多数有机溶剂。
Density1.238
Melting Point65-69°C

别名和识别编码

Chemical Name乐杀螨
Synonym (6-(1-Methyl-propyl)-2,4-dinitro-fenyl)-3,3-dimethyl-acrylaat (6-(1-Metil-propil)-2,4-dinitro-fenil)-3,3-dimetil-acrilato 2,4-Dinitro-6-sec-butylphe 2-(1-Methylpro 2-(1-methylpropyl)-4,6-dinitrophenyl 3-methyl-2-butenoate 2-sec-Butyl-4,6-dinitrophenyl 2-sec-Butyl-4,6-dinitrophenyl-3-methylcrotonat 2-sec-butyl-4,6-dinitrop 2-sec.-Butyl-4,6-dinitrophe 2-Butenoic acid, 3-methyl-, 2-(1-methylpropyl)-4,6-dinitrophenyl ester 2-SEC-BUTYL-4,6-DINITROPHENYL-3-METHYLCROTONATE 2-butenoic acid, 3-methyl-, 2-(1-methylpropyl)-4,6-dinitrophenylester 2-butenoicacid,3 2-sec-Butyl-4,6-dinitrophenyl 3-methyl-2-butenoate 2-sec-Butyl-4,6-dinitrophenyl 3-methylcrotonate 2-sec-Butyl-4,6-dinitrophenyl senecioate 2-sec-Butyl-4,6-
MDL NumberMFCD00055425
CAS Number485-31-4
PubChem Substance ID10234
Beilstein Registry Number2013712
EC Number207-612-9
Chemical Name Translation乐杀螨
Merck Number13,1224
Wiswesser Line Notation2Y1&R CNW ENW BOV1UY1&1
InChIInChI=1S/C15H18N2O6/c1-5-10(4)12-7-11(16(19)20)8-13(17(21)22)15(12)23-14(18)6-9(2)3/h6-8,10H,5H2,1-4H3
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分类

  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, Pesticides, Bactericides, Fungicides and Disinfectants, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009)
  • {SNA} Analytical Standards, Food and Cosmetic Component Standards, Pesticides, Bactericides, Fungicides and Disinfectants, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 分析/色谱
  • {SNA} Analytical Standards, Chromatography, Pesticides, Bactericides, Fungicides and Disinfectants, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 分析/色谱
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ester; 1fragment

产品应用

  • 该品为内吸性杀螨剂，对螨类有速效作用，对卵、幼虫和成虫的各个阶段均有效，对蜜蜂等采花昆虫和天敌无害，有特效性，对抗性螨类也有效。作为杀菌剂，对白粉病有效

相关文献及参考

  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSGQ5600000
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P312
  • P302+P352
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
WGK Germany3
Signal word Danger
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T,N
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Storage condition 0-6°C
Risk Statements
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R50/53
UN Number 2779
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 720 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : >800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   7,353,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    19

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   8,73,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 mg/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,185,1983

其他信息

  • 溶于多数有机溶剂，几乎不溶于水，在浓酸和稀碱中不稳定，带有轻微的芳香气味
  • RTECS号:GQ5600000
  • 用途:该品为内吸性杀螨剂，对螨类有速效作用，对卵、幼虫和成虫的各个阶段均有效，对蜜蜂等采花昆虫和天敌无害，有特效性，对抗性螨类也有效。作为杀菌剂，对白粉病有效。急性经口毒性LD50（mg/kg）：大白鼠150-225，雄小白鼠1600-3200。
  • 外观性质:褐色、有轻微芳香气味的固体。
  • 生产方法:2-仲丁基-4,6-二硝基酚与β,β二甲基丙烯酰氯在氮气保护下，于135℃搅拌反应5h，减压蒸馏除去过量的酰氯，剩余物用石油醚洗涤，经苯-己烷重结晶，得原药乐杀螨。原料消耗定额：2-仲丁基-4,6-二硝基酚750kg/t、β,β二甲基丙烯酰氯1120kg/t。
  • MOL 文件:485-31-4.mol
  • PackingGroup:III
  • HazardClass:6.1(b)
  • 图谱信息:乐杀螨(485-31-4)质谱(MS)

系列性分类

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