(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (+)-1-苄基-[(3R,4R)-双(二苯基膦)]吡咯烷(1,5-环辛二烯)四氟硼酸铑(I)
CAS 99143-48-3 MFCD05861620
化学结构图
SMILES: [Rh+].F[B-](F)(F)F.C(C1C=CC=CC=1)N1C[C@H]([C@@H](C1)P(C1C=CC=CC=1)C1C=CC=CC=1)P(C1C=CC=CC=1)C1C=CC=CC=1.C1C[CH][CH]CC[CH][CH]1 |^1:46,47,50,51|
化学属性
| Mol. Formula | C43H45BF4NP2Rh |
|---|---|
| Mol. Weight | 827.48 |
别名和识别编码
| Chemical Name | (+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate |
|---|---|
| Synonym | (3R-反式)-3,4-双(二苯基膦)-1-(苯基甲基)吡咯烷铑络合物 catASium® D(R)Rh (+)-1-苄基-[(3R,4R)-双(二苯基膦)]吡咯烷(1,5-环辛二烯)四氟硼酸铑(I) (3R-反式)-3,4-双(二苯基膦)-1-(苯基甲基)吡咯烷铑络合物 catASium® D(R)Rh |
| MDL Number | MFCD05861620 |
| CAS Number | 99143-48-3 |
| Chemical Name Translation | (+)-1-苄基-[(3R,4R)-双(二苯基膦)]吡咯烷(1,5-环辛二烯)四氟硼酸铑(I) |
| PubChem Substance ID | 329760529 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, catASium
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, catASium
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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