N-Methylhomopiperazine N-甲基高哌嗪

CAS 4318-37-0 MFCD00059810

化学结构图

4318-37-0
SMILES: CN1CCCNCC1

化学属性

Mol. FormulaC6H14N2
Mol. Weight114.19
Refractive index1.4750 to 1.4790
Boiling Point157.4°C at 760 mmHg
Density0.918
Flash Point45°C

别名和识别编码

Chemical NameN-Methylhomopiperazine
CAS Number4318-37-0
Alfabeta NameMETHYLDIAZEPANE 114---,
MDL NumberMFCD00059810
Synonym 1-Methyl-1,4-diazepane {LY} 1-Methyl-1,4-diazepane {} {LY} 1-Methyl-1,4-diazepane {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1,4-diazepane {} {} {} {} {} {} {} {} {} {
PubChem Substance ID228349
Reaxys-RN103021
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name TranslationN-甲基高哌嗪
LabNetwork Molecule IDLN00008972
InChIInChI=1S/C6H14N2/c1-8-5-2-3-7-4-6-8/h7H,2-6H2,1H3
Canonical SMILESCN1CCNCCC1
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分类

  • {SNA} Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Piperazines
  • Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Piperazines

相关文献及参考

  • Beil. 23 ,IV,389
  • IR-Spectra (3), 224:A / Structure Index 1 , 56:C:9

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes 8 C
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2920
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
Packing GroupII
Hazard Class8/3
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:4318-37-0.mol
  • N-甲基高哌嗪价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0751 N-甲基高哌嗪 1-Methylhomopiperazine 5ML 454元 2014/06/02 M0751 N-甲基高哌嗪 1-Methylhomopiperazine 25ML 1470元
  • 上游原料:乙醇 --> 氢氧化钠 --> 甲醇 --> 氨 --> 1,4-二氧六环 --> 氢 --> 二碳酸二叔丁酯 --> 镍 --> 叔丁醇 --> 丙烯腈 --> 甲基磺酰氯 --> 二苯醚 --> N-甲基-2-羟基乙胺 --> N-甲基乙二胺
  • MSDS 信息:Hexahydro-1-methyl-1H-1,4-diazepine(4318-37-0).msds
  • 图谱信息:N-甲基高哌嗪(4318-37-0)Raman光谱 N-甲基高哌嗪(4318-37-0)红外图谱(IR1) N-甲基高哌嗪(4318-37-0)核磁图( 13 CNMR) N-甲基高哌嗪(4318-37-0)质谱(MS) N-甲基高哌嗪(4318-37-0)红外图谱(IR2) N-甲基高哌嗪(4318-37-0)核磁图( 1 HNMR)
  • TCI Shanghai:N-甲基高哌嗪 1-Methylhomopiperazine,>;98.0%(GC)(T)(4318-37-0)
  • 检测方法:GC,NMR
  • Sigma Aldrich:4318-37-0(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperazines 哌嗪
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperazines 哌嗪
  5. C4 to C8 - Piperazines

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