(3S,CIS)-(+)-2,3-DIHYDRO-3-ISOPROPYL-7A-METHYLPYRROLO[2,1-B] OXAZOL-5(7AH)-ONE (3S-顺式)-(+)-2,3-二氢-3-异丙基-7a-甲基吡咯并[2,1-b]氧氮杂茂-5(7aH)-酮

CAS 116910-11-3 MFCD06496252

化学结构图

116910-11-3
SMILES: CC(C)[C@H]1CO[C@]2(C)C=CC(=O)N21

化学属性

Mol. FormulaC10H15NO2
Mol. Weight181.23
Melting Point46-49 °C(lit.)

别名和识别编码

Chemical Name(3S-cis)-(+)-2,3-Dihydro-3-isopropyl-7a-methylpyrrolo[2,1-b]oxazol-5(7aH)-one
MDL NumberMFCD06496252
PubChem Substance ID24869479
CAS Number116910-11-3
Chemical Name Translation(3S-顺式)-(+)-2,3-二氢-3-异丙基-7a-甲基吡咯并[2,1-b]氧氮杂茂-5(7aH)-酮
Synonym (3S-顺式)-(+)-2,3-二氢-3-异丙基-7a-甲基吡咯并[2,1-b]氧氮杂茂-5(7aH)-酮
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Others
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Others
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Other Heterocyclic Building Blocks

相关文献及参考

  • 1. Romo, D. Meyers, A.I. Tetrahedron 47 , 9503, (1991)
  • 2. Fray, A.H. Meyers, A.I. J. Org. Chem. 61 , 3362, (1996)
  • 3. Meyers, A.I. et al. J. Org. Chem. 60 , 4359, (1995)
  • 4. Munchhoff, M.J. Meyers, A.I. J. Org. Chem. 60 , 7084, (1995)
  • 5. Munchhoff, M.J. Meters, A.I. J. Org. Chem. 60 , 7086, (1995)
  • 6. Sandham, D.A. Meyers, A.I. J. Chem. Soc., Chem. Commun. , 2511, (1995)
  • 7. Andres, C.S. Meyers, A.I. Tetrahedron Lett. 36 , 3491, (1995)
  • 8. Andres, C.J. et al. Tetrahedron Lett. 60 , 3189, (1995)
  • 9. Brengel, G.P. Meyers, A.I. J. Org. Chem. 61 , 3230, (1996)
  • 10. Meyers, A.I. et al. J. Org. Chem. 61 , 2586, (1996) 摘要

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Others - Heterocyclic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Others - Heterocyclic Building Blocks

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