2,4-D-Dimethylammonium 2,4-二氯苯氧乙酸二甲胺盐

CAS 2008-39-1 MFCD00072481

化学结构图

2008-39-1
SMILES: CNC.O=C(O)COc1ccc(Cl)cc1Cl

化学属性

Mol. FormulaC18H6Cl2O3.C2H7N
Mol. Weight386.24
Appearance 2,4-二氯苯氧乙酸二甲胺盐(2008-39-1)为浅棕色液体

别名和识别编码

Chemical Name2,4-Dichlorophenoxyacetic Acid Dimethylamine Salt
EC Number217-915-8
Synonym (2,4-DICHLOROPHENOXY)ACETIC ACID, DIMETHYLAMINE SALT (2,4-dichlorophenoxy)-aceticacicmpdwithdimethylamine(1:1)[qr] (2,4-dichlorophenoxy)-aceticacicmpdwithn-methylmethanamine(1:1)[qr] (2,4-dichlorophenoxy)-aceticacicompd.withdimethylamine(1:1) (2,4-dichlorophenoxy)aceticaciddimethylamine (2,4-dichlorophenoxy)aceticaciddimethylamine[qr] (2,4-dichlorophenoxy)aceticaciddimethylaminesalt[qr] (2,4’dichlorophenoxy)-aceticacicompd.withn-methylmethanamine(1:1) 2,4 D amine 2,4-D DIMETHYLAMINE SALT 2,4-D amine 2,4-D dimethylamine salt; Dimethylammonium 2,4-dichlorophenoxyacetate 2,4-D-amine, sodium salt 2,4-DDimethylamine 2,4-D二甲胺盐 2,4-D胺 2,4-d,dimethylamine 2,4-dacetate 2,4-damine 2,4-ddimethylamines
CAS Number2008-39-1
MDL NumberMFCD00072481
Chemical Name Translation2,4-二氯苯氧乙酸二甲胺盐
Wiswesser Line NotationGR CG DO1VON1&1
PubChem Substance ID16180
InChIInChI=1S/C8H6Cl2O3.C2H7N/c9-5-1-2-7(6(10)3-5)13-4-8(11)12;1-3-2/h1-3H,4H2,(H,11,12);3H,1-2H3
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安全信息

Hazard Codes Xn
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
Packing GroupIII
Hazard Class6.1(b)
UN Number 3345
RTECSAG8400000
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   31(7-9),383,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 625 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Kidney, Ureter, Bladder - urine volume increased
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 36(11),33,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2115 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C98,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   31(7-9),383,1966

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 1,241,1986

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 14 mg/kg/15D (Continuous)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 57(2),66,1992

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   22,14,1972

Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H332 Harmful if inhaled 吸入有害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P333+P317
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • MOL 文件:2008-39-1.mol
  • MSDS 信息:2,4-D dimethylamine salt(2008-39-1).msds
  • 注意事项:[1]该药在大剂量下为除草剂,低剂量使用为植物生长调节剂,因此使用时必须在规定的浓度范围内使用,以免造成药害而减产。在没有使用过的地区,应通过小面积作物试验,取得经验后再扩大施用 [2]留作种子用的农田禁用本品,以免造成植物生长变态
  • 用途一:主要用于防除水稻及小麦田的双子叶杂草
  • Sigma Aldrich:2008-39-1(sigmaaldrich)
  • 上游原料:二甲胺 --> 氯乙酸 --> 2,4-二氯苯氧乙酸
  • 中毒症状:消化道症状,严重时对肝、肾损伤。
  • 急救治疗:对症治疗。

系列性分类


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