2-Bromo-2-Nitropropane 2-溴-2-硝基丙烷
CAS 5447-97-2 MFCD00007389
化学结构图
SMILES: CC(C)(Br)[N+](=O)[O-]
化学属性
| Mol. Formula | C3H6BrNO2 |
|---|---|
| Mol. Weight | 168 |
| Refractive index | n20/D 1.464(lit.) |
| Boiling Point | 48 °C/15 mmHg(lit.) |
| Density | 1.582 g/mL at 25 °C(lit.) |
| Flash Point | 61°(141°F) |
| TSCA | No |
别名和识别编码
| Chemical Name | 2-Bromo-2-Nitropropane |
|---|---|
| CAS Number | 5447-97-2 |
| PubChem Substance ID | 79531 |
| EC Number | 226-668-5 |
| MDL Number | MFCD00007389 |
| Beilstein Registry Number | 1746626 |
| Synonym | 2-Nitro-2-bromopropane 2-溴-2-硝基丙烷 2-溴-2-硝基丙烷, 98+% Propane, 2-bromo-2-nitro- 2-Bromo-2-nitropropane, 98+% 2-溴2-硝基丙烷 2-BROMO-2-NITROPROPANE |
| Chemical Name Translation | 2-溴-2-硝基丙烷 |
| InChIKey | OADSZWXMXIWZSQ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN02141434 |
| InChI | InChI=1S/C3H6BrNO2/c1-3(2,4)5(6)7/h1-2H3 |
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分类
- Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks
- {SNA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks
相关文献及参考
- Aldrich MSDS 1 , 270:D / Corp MSDS 1 (1), 558:A / FT-IR 1 (1), 403:B / FT-IR 2 (1), 633:D / FT-NMR 1 (1), 627:C / IR-Spectra (2), 211:B / IR-Spectra (3), 237:D / RegBook 1 (1), 439:D / Structure Index 1 , 63:A:6 / Vapor Phase 3 , 484:D
- Beil. 1 ,116
- With malonate-type nucleophiles gives ß-nitro esters which, on heating with an alkali metal salt in a dipolar aprotic solvent, undergo elimination to alkenes. The sequence can be carried out in one pot: J. Org. Chem., 48, 3678 (1983); Chem. Lett., 757 (1976):
安全信息
GHS Symbol
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
其他信息
- Acros Organics:2-Bromo-2-nitropropane, 97%(5447-97-2)
- MOL 文件:5447-97-2.mol
- Sigma Aldrich:5447-97-2(sigmaaldrich)
- Alfa Aesar:2-溴-2-硝基丙烷,98% 2-Bromo-2-nitropropane, 98%(5447-97-2)
- 2-溴2-硝基丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 309770050 2-溴2-硝基丙烷 2-Bromo-2-nitropropane 97% 5 GR 276元 2010/05/25 A18385 2-溴-2-硝基丙烷, 98% 2-Bromo-2-nitropropane, 98% 5g 295元 2010/05/25 A18385 2-溴-2-硝基丙烷, 98% 2-Bromo-2-nitropropane, 98% 25g 899元
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