1-Methyl-1-Phenylhydrazine 1-甲基-1-苯肼

CAS 618-40-6 MFCD00007627

化学结构图

618-40-6
SMILES: CN(N)c1ccccc1

化学属性

Mol. FormulaC7H10N2
Mol. Weight122.17
Refractive index1.5810 to 1.5850
Boiling Point54-55 °C at 0.3 mmHg
Density1.038 g/mL at 25 °C(lit.)
Flash Point92°C(lit.)
TSCAYes
Solubility微溶
Appearance 无色或浅黄色液体。沸点227℃（99.3kPa），131℃（4.67kPa），相对密度1.0404（20/4℃），折光率1.5691，闪点96℃。能与乙醇、乙醚、氯仿和苯混溶，微溶于水。

别名和识别编码

Chemical Name1-Methyl-1-Phenylhydrazine
Synonym 1-Methyl-1-phenylhydrazine {LY} 1-Methyl-1-phenylhydrazine {} {LY} 1-Methyl-1-phenylhydrazine {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number618-40-6
PubChem Substance ID36299
EC Number210-547-9
Beilstein Registry Number15,117
MDL NumberMFCD00007627
Reaxys-RN507683
Chemical Name Translation1-甲基-1-苯肼
InChIKeyMWOODERJGVWYJE-UHFFFAOYSA-N
LabNetwork Molecule IDLN01354733
InChIInChI=1S/C7H10N2/c1-9(8)7-5-3-2-4-6-7/h2-6H,8H2,1H3
Canonical SMILESNN(C)C1=CC=CC=C1
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分类

  • Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: III/20a
  • Short: III/38B
  • Short: IV/6

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P350
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
RTECSMV7712000
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Packing GroupIII
Hazard Class6.1(b)
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number 2810

其他信息

  • 用途一:用于有机合成，用于酮和糖的测定。
  • 下游产品:2,3,4,5-四氢-5-甲基-1H-吡啶并[4,3-b]吲哚-1-酮 --> 5,6-二氢-4-(2-甲基-2-苯基肼基)-2-1H-吡啶酮
  • Sigma Aldrich:618-40-6(sigmaaldrich)
  • 上游原料:锌粉 --> N-甲基苯胺
  • 方法一:由N-亚硝基甲基苯胺还原而得。将锌粉和水搅成悬浮液，在10-20℃缓缓加入N-亚硝基甲基胺和冰醋酸配成的溶液，加毕，在室温下继续搅拌1h。然后加热到80℃，趁热滤出未反应的锌粉。滤液冷却后加入过量的40%氢氧化钠溶液，使沉淀出来的氢氧化钠重新溶解。分出油层，减压蒸馏，收集106-109℃（1.73kPa）馏分，即为成品。收率50%以上。
  • Alfa Aesar:1-甲基-1-苯肼,97% 1-Methyl-1-phenylhydrazine, 97%(618-40-6)
  • 1-甲基-1-苯肼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0399 1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine 25G 1670元 2010/06/21 354790050 1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine 96% 5 GR 1508元 2010/06/21 354790250 1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine 96% 25 GR 4465元
  • MOL 文件:618-40-6.mol
  • F:8-10-23
  • Acros Organics:1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine, 96%(618-40-6)
  • TCI Shanghai:1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine,>;95.0%(GC)(618-40-6)
  • 图谱信息:1-甲基-1-苯肼(618-40-6)红外图谱(IR2) 1-甲基-1-苯肼(618-40-6)核磁图( 13 CNMR) 1-甲基-1-苯肼(618-40-6)红外图谱(IR1) 1-甲基-1-苯肼(618-40-6)核磁图( 1 HNMR) 1-甲基-1-苯肼(618-40-6)质谱(MS)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Guanidines

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