2-Methyl-6-Nitroaniline 2-甲基-6-硝基苯胺

CAS 570-24-1 MFCD00007744

化学结构图

570-24-1
SMILES: Cc1cccc([N+](=O)[O-])c1N

化学属性

Mol. FormulaC7H8N2O2
Mol. Weight152.15
Melting Point93-96°C
Density1.422
TSCANo
Flash Point110 ºC
Solubility<0.1 G/100 ML AT 23 ºC
Appearance 橙色或黄色棱柱状结晶。熔点97℃。溶于醇、醚、苯和氯仿，微溶于水。
Boiling Point301.4°C at 760 mmHg

别名和识别编码

Chemical Name2-Methyl-6-Nitroaniline
CAS Number570-24-1
Alfabeta NameMETHYLNITROANILINE 26---
MDL NumberMFCD00007744
Synonym 2-Methyl-6-nitroaniline {LY} 2-Methyl-6-nitroaniline {} {LY} 2-Methyl-6-nitroaniline {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-6-nitroaniline {} {} {} {} {} {} {} {}
Beilstein Registry Number1868029
PubChem Substance ID87573801
EC Number209-329-6
Reaxys-RN1868029
Chemical Name Translation2-甲基-6-硝基苯胺
Canonical SMILESNC1=C([N+]([O-])=O)C=CC=C1C
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分类

  • Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SA} Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Aldrich MSDS 1 , 1275:A / Corp MSDS 1 (2), 2388:D / FT-IR 1 (1), 1348:B / FT-IR 2 (2), 2282:A / FT-NMR 1 (2), 713:A / IR-Spectra (3), 814:A / IR-Spectra (2), 713:F / NMR-Reference 2 (1), 1149:B / RegBook 1 (1), 1567:L / Structure Index 1 , 244:C:4 / Vapor Phase 3 , 1197:B
  • Beil. 12 ,IV,1807
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.

安全信息

Warnings IRRITANT
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P352+P312
  • P302+P352+P312+P361+P364
  • P304+P340+P311
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
GHS Symbol
Signal word Danger
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H331 Toxic if inhaled 吸入中毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Hazard Codes 6.1 T,N T,N,Xi
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R51/53
UN Number 2660
Packing GroupIII
Hazard Class6.1
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 方法一:邻甲基乙酰苯胺用70%硝酸硝化得到的硝基邻甲基乙酰苯胺，与浓盐酸一起加热至沸，反应产物进行水蒸气蒸馏，得到6-硝基邻甲苯胺，收率约50%。
  • Sigma Aldrich:570-24-1(sigmaaldrich)
  • 上游原料:2-甲基乙酰苯胺
  • 下游产品:4-溴甲基-2,1,3-苯并噻重氮 --> 2,1,3-苯并噻二唑-4-甲酸 --> 2,1,3-苯并噻二唑-4-甲醛 --> 7-氨基吲唑 --> 7-硝基吲唑
  • 海关编码:29214300
  • Hazard Note:Toxic
  • MOL 文件:570-24-1.mol
  • 2-甲基-6-硝基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010363 2-甲基-6-硝基苯胺;6-硝基邻甲苯胺;2-氨基-3-硝基甲苯 50g 498元 2011/04/16 N0467 2-甲基-6-硝基苯胺 2-Methyl-6-nitroaniline 250G 5020元 2011/04/16 N0467 2-甲基-6-硝基苯胺 2-Methyl-6-nitroaniline 25G 835元
  • F:10
  • MSDS 信息:2-Amino-3-nitrotoluene (570-24-1).msds
  • TCI Shanghai:2-甲基-6-硝基苯胺 2-Methyl-6-nitroaniline,>;99.0%(GC)(570-24-1)
  • 图谱信息:2-甲基-6-硝基苯胺(570-24-1)红外图谱(IR1) 2-甲基-6-硝基苯胺(570-24-1)红外图谱(IR2) 2-甲基-6-硝基苯胺(570-24-1)核磁图( 13 CNMR) 2-甲基-6-硝基苯胺(570-24-1)核磁图( 1 HNMR) 2-甲基-6-硝基苯胺(570-24-1)质谱(MS)
  • Acros Organics:2-甲基-6-硝基苯胺 2-Methyl-6-nitroaniline, 99%(570-24-1)
  • 用途一:用于有机合成。

系列性分类

  1. C7 - Amines
  1. C10 to C11 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C2 to C6

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