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• 试剂商城
• 直接询价

分类

• {SNA} 2002/61/EC, All alphabetical sorted, Alpha Sort, Alphabetical Index of Analytical Standards, Amines, A
• 2002/61/EC, Alpha Sort, Alphabetic, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Aryl Amines MAK III, Category 2, Chemical Class, Chromatography, Environmental Standards, European Community: ISO, DIN and DL 152, Food & Beverage Standards, Food Dyes, Food Residue Analysis, M, META - METH, Method Specific, Oeko-Tex Standard 100, Volatiles/ Semivolatiles

产品应用

• 本品是以种染料中间体。在直接染料方面用于合成C.I.29050；29065；27885等，在酸性染料方面用于合成C.I.14940；14965等，还用于制造分散大红GC；直接耐晒蓝3RLL；直接黑D；活性黄棕K-GR；阳离子黄4G等。

相关文献及参考

• Beilstein:13(2)338

安全信息

GHS Symbol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 364 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Brain and Coverings - tumors
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-142,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 355 gm/kg/92W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-142,1979

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2961 gm/kg/92W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 27,91,1982

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3640 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1450 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HURC** Huntingdon Research Center Reports.  (Box 527, Brooklandville, MD
   21022)  Volume(issue)/page/year: -,-,1972

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 2 mg/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 62500 ng
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 595 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 412,155,1998

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - rat Embryo
DOSE/DURATION           : 31 ug/plate
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 1,190,1981

其他信息

• 急性毒性:口服-大鼠 LD50: 1450 毫克/公斤
• 下游产品:直接混纺蓝D-3GL --> 直接混纺黄D-3RNL --> 活性黄84 --> 直接绿26 --> 直接紫9 --> 直接黄 RL --> 直接灰D --> C.I.直接紫51 --> 直接红 6BL --> 直接蓝 3RL --> 直接黄L-5R --> 3-氨基-4-甲氧基甲苯-6-磺酸
• 毒性分级:中毒
• Acros Organics:2-甲氧基-5-甲基苯胺 2-Methoxy-5-methylaniline, 95%(120-
• 刺激数据:皮肤-兔子 500 毫克/24小时 轻度; 眼睛-兔子 100 毫克/24小时 中度
• 图谱信息:2-甲氧基-5-甲基苯胺(120-71-8)红外图谱(IR1) 2-甲氧基-5-甲基苯胺(120-71-8)红外图谱(IR2) 2-甲氧基-5-甲基苯胺(120-71-8)红外图谱(IR3) 2-甲氧基-5-甲基苯胺(120-71-8)核磁图( 13 CNMR) 2-甲氧基-5-甲基苯胺(120-71-8)核磁图( 1 HNMR) 2-甲氧基-5-甲基苯胺(120-71-8)质谱(MS)
• MOL 文件:120-71-8.mol
• 类别:有毒物品
• 溶于醇，醚，氯仿及稀盐酸中，难溶于水，不溶于苯。
• 用途三:本品是以种染料中间体。在直接染料方面用于合成C.I.29050；29065；27885等，在酸性染料方面用于合成C.I.14940；14965等，还用于制造分散大红GC；直接耐晒蓝3RLL；直接黑D；活性黄棕K-GR；阳离子黄4G等。
• 用途二:本品是一种染料中间体。
• 蒸气密度:4.7 (vs air)
• 2-甲氧基-5-甲基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0115 2-甲氧基-5-甲基苯胺 2-Methoxy-5-methylaniline 25G 246元 2014/06/02 M0115 2-甲氧基-5-甲基苯胺 2-Methoxy-5-methylaniline 500G 1810元 2010/06/21 332080050 2-甲氧基-5-甲基苯胺
• 方法一:1.由对氯甲苯硝化、甲氧基化、还原而得。在15-20℃将混酸加入对氯甲苯中，在30℃搅拌2h，用水稀释，分离废酸，水洗得4-氯-3-硝基甲苯（收率30.6%）和4-氯-2-硝基甲苯（收率56.7%），用分馏和结晶法将两者分离，得4-氯-3-硝基甲苯。将其与甲醇及甲醇钠溶液反应，用硫酸中和分离，得3-硝基-4-甲氧基甲苯，收率85.6
• Sigma Aldrich:120-71-8(sigmaaldrich)
• 储运特性:库房通风低温干燥; 与食品原料分开储运
• F:9
• 灭火剂:雾状水、二氧化碳、砂土、干粉
• 用途一:适用于直接、分散、活性染料的合成
• TCI Shanghai:2-甲氧基-5-甲基苯胺 2-Methoxy-5-methylaniline,>;98.0%(GC)(T)(1
• 上游原料:氢氧化钠 --> 硫酸二甲酯 --> 硫化钠 --> 对氯甲苯 --> 甲醇钠溶液 --> 4-氯-2-硝基甲苯 --> 对甲苯甲醚 --> 3-硝基-4-氯甲苯 --> N-苄基二乙胺
• MSDS 信息:邻氨基对甲苯甲醚(120-71-8).msds
• 方法一:1.由对氯甲苯硝化、甲氧基化、还原而得。在15-20℃将混酸加入对氯甲苯中，在30℃搅拌2h，用水稀释，分离废酸，水洗得4-氯-3-硝基甲苯（收率30.6%）和4-氯-2-硝基甲苯（收率56.7%），用分馏和结晶法将两者分离，得4-氯-3-硝基甲苯。将其与甲醇及甲醇钠溶液反应，用硫酸中和分离，得3-硝基-4-甲氧基甲苯，收率85.6%。用水、铁粉、甲酸还原后，再用溶剂汽油多次萃取蒸馏而得。2.由对甲酚硝化得到2-硝基-4-甲酚，再与硫酸二甲酯甲基化为3-硝基-4-对甲氧基甲苯，最