(1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]Heptane-2,3-Dione (1R,4S)-1,7,7-三甲基双环[2.2.1]庚烷-2,3-二酮

CAS 10334-26-6 MFCD00082863

化学结构图

10334-26-6
SMILES: CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O

化学属性

Mol. FormulaC10H14O2
Mol. Weight166
Melting Point200.0 to 204.0 deg-C
TSCANo

别名和识别编码

Chemical Name(1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]Heptane-2,3-Dione
MDL NumberMFCD00082863
CAS Number10334-26-6
Synonym (1R)-(-)-2,3-莰烷二酮 2,3-莰烷二酮 (1R)-(-)-2,3-莰烷二酮 2,3-莰烷二酮 (1R)-(-)-樟脑醌 (1R)-(-)-2,3-Bornanedione
Beilstein Registry Number7(4)2039
PubChem Substance ID87566480
Reaxys-RN4666277
Chemical Name Translation(1R,4S)-1,7,7-三甲基双环[2.2.1]庚烷-2,3-二酮
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Ketones, Organic Building Blocks

相关文献及参考

  • For use in the kinetic resolution of 1,2-diols by means of diastereomeric acetal formation, see: J. Chem. Soc., Chem. Commun., 1600 (1984).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352+P333+P313+P362+P364
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P342+P311
  • P305+P351+P338
  • P333+P313
  • P304+P340
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312+P330
  • P302+P350
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Danger
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Ketones - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Ketones - Organic Building Blocks
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Terpenes

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