Chlorodihydrido[bis(2-diisopropylphosphino)ethylamine]iridium(III), mixture of isomers 氯化二氢[双(2-二异丙基膦)乙胺]铱(III)，同分异构体混合物

CAS N/A MFCD08457641

化学结构图

N/A
SMILES: CC(C)P(CCNCCP(C(C)C)C(C)C)C(C)C.Cl[IrH2]

化学属性

Mol. FormulaC16H39ClIrNP2
Mol. Weight535.11
Melting Point248-253 °C

别名和识别编码

Chemical NameChlorodihydrido[bis(2-diisopropylphosphino)ethylamine]iridium(III), mixture of isomers
Synonym [2-[bis(1-methylethyl)phosphino-KP]-N-[2-[bis(1-methylethyl)phosphino-KP]ethyl]ethanamine-KN]chlorodihydroiridium 氯化二氢[双(2-二异丙基膦)乙胺]铱(III)，同分异构体混合物
MDL NumberMFCD08457641
PubChem Substance ID24884704
Chemical Name Translation氯化二氢[双(2-二异丙基膦)乙胺]铱(III)，同分异构体混合物
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分类

  • {SNA} Aminophosphine Ligands, Asymmetric Synthesis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Iridium Catalysts, Privileged Ligands and Complexes
  • Aminophosphine Ligands, Asymmetric Synthesis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents,

相关文献及参考

  • 1. N. Andrushko, et al., ChemCatChem 2 , 640-643, (2010)
  • 2. X. Chen, et al., Dalton Trans. 8 , 1407-1410, (2009)
  • 3. Z. E. Clarke, et al., Organometallics 25 , 4113-4117, (2006)

安全信息

WGK Germany3
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Aminophosphine Ligands - Privileged Ligands and Complexes

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