Phosphorus Oxychloride 三氯氧磷

CAS 10025-87-3 MFCD00011443

化学结构图

10025-87-3
SMILES: O=P(Cl)(Cl)Cl

化学属性

Mol. FormulaCl3OP
Mol. Weight153.32
Density1.645
Vapor Density5.3 (vs air)
Boiling Point105.8°
Vapor Pressure104 mmHg ( 50 °C)
Melting Point1.25°
Refractive index1.460
TSCAYes
Solubility起反应 EXOTHERMICALLY
Appearance colorless liq.
Stabilitymoisture sensitive
pH:A

别名和识别编码

Chemical NamePhosphorus Oxychloride
Synonym Phosphoryl trichloride 三氯氧磷(V) trichlorophosphorus oxide Phosphorus oxide trichloride Phosphorus(V) trichloride oxide phosphorus chloride oxide(pocl3) Phosphoric trichloride; Phosphoryl chloride; Phosphoryl oxychloride; Phosphoryl trichloride Phosphorylchlorid Phosphorus oxytrichloride phosphorus trichloride oxide Phosphoroxychlorid Phosphorusoxy chloride Phosphorylchlorid FO Optipur® Phosphorus oxide chloride Phosphorsäuretrichlorid Trichlorophosphorus oxide Phosphoroxichlorid Phosphortrichloridoxid Phosphorous chloride oxide (POCl3) Phosphoroxychloride phosphoric trichloride phosphoryl chloride Phosphorus chloride oxide (PCl3O) trichlorophosphine oxide Phosphoric chloride phosphoryl trichloride Phosphorus (V) trichloride oxide Phosphoryltrichlorid Phosphorus chloride oxide (POCl3) Phosphoroxidtrichlorid Oxychlorid fosforecny Phosphoroxidchlorid Phosphonyl trichloride Phosphorus monoxide trichloride Phosphorus oxychloride Phosphoroxytrichloride Fosforoxychlorid Trichlorophosphine oxide
EC Number233-046-7
MDL NumberMFCD00011443
PubChem Substance ID24859264
CAS Number10025-87-3
Merck Number14,7349
Chemical Name Translation三氯氧磷
Wiswesser Line NotationP O G3
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SA} C-X Bond Formation (Halogen), Chemical Synthesis, Chlorination, Others, Oxidizing Agents, Synthetic Reagents
  • {SNA} C-X Bond Formation (Halogen), Chemical Synthesis, Chlorination, Essential Chemicals, Inorganic Salts, Solutions and Reagents, Reagent Plus, Research Essentials, Synthetic Reagents

相关文献及参考

  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: II/5 Title: Molecular Acoustics Author: Schaaffs, W. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/5 Year: 1967 ISBN: 3-540-03897-3 ISBN: 978-3-540-03897-9 Internet Resource: DOI:10.1007/b19950 RefComment: 321 figs., XII, 286 pages, Hardcover
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTH4897000
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Packing GroupI
UN Number 1810 UN1810
Risk Statements
  • R48/23
  • R26 Very toxic by inhalation 吸入极毒
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害
  • R35 Causes severe burns 会导致严重灼伤
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition Moisture Sensitive
Hazard Codes T+;C T+,C
Warnings 危化品目录(2015) 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 53 ppm/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Behavioral - irritability
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   25,470,1964

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Liver - other changes
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534840

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 36 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - other changes
   Liver - other changes
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534840

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 32 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZPAK "Sbornik Vysledku Toxixologick

Restrict 危险品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. Reagent Plus - Inorganic Salts, Solutions and Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Halogen) 卤代烃
  4. Bromination - C-X Bond Formation (Halogen)
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Halogen) 卤代烃
  4. Chlorination - C-X Bond Formation (Halogen)
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Halogen) 卤代烃
  4. Iodination - C-X Bond Formation (Halogen)
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Osmium - Oxidation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Others - Oxidation
  1. phosphoric acid halide
  1. CVD & ALD Precursors
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Halides for CVD & ALD
  2. Phosphorus