N,N-Diethylaniline, 99% N,N-二乙基苯胺

CAS 91-66-7 MFCD00009042

化学结构图

91-66-7
SMILES: CCN(CC)c1ccccc1

化学属性

Mol. FormulaC10H15N
Mol. Weight149.23
Density0.938
Refractive index1.5400 to 1.5430
Autoignition Point1166 °F
Vapor Density5.2 (vs air)
Boiling Point-
Vapor Pressure1 mmHg ( 49.7 °C)
Melting Point-38
Flash Point97.78°C
TSCAYes
Solubility14 G/L (12 ºC)
Stability对光敏感
pH:A

别名和识别编码

Chemical NameN,N-Diethylaniline, 99%
CAS Number91-66-7
EC Number202-088-8
Beilstein Registry Number742483
MDL Number-
Synonym N,N-Diethylbenzenamine {LY} N,N-Diethylbenzenamine {} {LY} N,N-Diethylbenzenamine {} {} {LY} N,N-Diethylbenzenamine {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylbenzenamine {} {} {} {} {} {} {} {} {} {} {} {}
Merck Number3114
PubChem Substance ID7061
Reaxys-RN742483
Chemical Name TranslationN,N-二乙基苯胺
Wiswesser Line Notation2N2&R
LabNetwork Molecule IDLN00195757
InChIInChI=1S/C10H15N/c1-3-11(4-2)10-8-6-5-7-9-10/h5-9H,3-4H2,1-2H3
Canonical SMILESCCN(CC)C1=CC=CC=C1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, C-D, Puriss p.a., Puriss p.a.
  • {SNA} Amines, Building Blocks, C10, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Analytical Reagents for General Use, C-D, Puriss p.a., Puriss p.a.,

产品应用

  • 用作分析试剂和检测锌和锰。

相关文献及参考

  • Merck: 14,3114 Beilstein:12,164
  • Short: II/27B
  • Merck: 14,3114
  • Short: II/3

安全信息

Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S37 Wear suitable gloves 戴适当手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P301+P310
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P403+P235
  • P304+P340+P312
  • P305+P351+P338+P337+P313
  • P308+P311
Hazard statements
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H301+H311+H331
  • H227 Combustible liquid 可燃液体
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSBX3400000
Packing GroupIII
UN Number
Hazard Codes T,N
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1920 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0282-0430

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 2570 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 48(6),22,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 420 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AGGHAR Archiv fuer Gewerbepathologie und Gewerbehygiene.  (Berlin, Ger.)
   V.1-18, 1930-61.  For publisher information, see IAEHDW.
   Volume(issue)/page/year: 15,447,1957

Restrict 危险品

其他信息

  • 上游原料:乙醇 --> 氨基苯
  • 方法一:由苯胺与氯乙烷反应而得。原料消耗定额：苯胺645kg/t、氯乙烷（95%）1473kg/t、烧碱（42%）1230kg/t、苯酐29kg/t。
  • 防护措施:有毒，其毒性比N，N-二甲基苯胺稍小（N，N-二甲基苯胺对家兔经口LD 280 mg/kg），但仍为剧毒品。吸入其蒸气和经皮肤吸收而引起中毒，具有血液毒、神经毒和致癌性。应加强防护措施，使生产设备密闭，现场通风良好，操作人员应穿戴防护用具。
  • 用途一:用于染料中间体、乳胶促进剂、制药、农药等
  • Sigma Aldrich:91-66-7(sigmaaldrich)
  • TCI Shanghai:N,N-二乙基苯胺 N,N-Diethylaniline,>;99.0%(GC)(91-66-7)
  • Acros Organics:N,N-二乙基苯胺 N,N-Diethylaniline, 99%(91-66-7)
  • 用途三:二乙基苯胺主要用于生产偶氮染料，三苯基甲烷染料，可制备碱性艳绿、碱性紫、酸性湖蓝V等；也是制药工业、彩色影片显影剂的中间体。用作分析试剂和检测锌和锰。
  • 蒸气密度:5.2 (vs air)
  • 类别:有毒物品
  • N,N-二乙基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80049218 N，N-二乙基苯胺;二乙氨基苯 500ml 77.1元 2011/08/23 80049228 N，N-二乙基苯胺;二乙氨基苯 500ml 64.4元 2011/04/16 D0475 N,N-二乙基苯胺 N,N-Diethylaniline 25ML 117元
  • 灭火剂:泡沫、二氧化碳、砂土
  • MOL 文件:91-66-7.mol
  • Alfa Aesar:N,N-二乙基苯胺,99% N,N-Diethylaniline, 99%(91-66-7)
  • 微溶于醇、醚和氯仿。1g该品可溶于70ml12℃的水。有特殊气味(特臭)，能随水蒸气挥发。
  • 可燃性危险特性:明火可燃; 与氧化剂起作用; 燃烧产生有毒氮氧化物烟雾
  • 下游产品:花椒毒醇 --> 4,6-二氨基-5-硝基嘧啶 --> 2-氨基-4,6-二氯-5-甲酰胺基嘧啶 --> 2-氯-4-二甲基氨基-5-溴嘧啶 --> 4,5‘,8-三甲基]补骨脂素 --> 2,4-二氯-5-氰基嘧啶 --> 2,4-氨基嘧啶-5-羧酸 --> 2-溴呋喃 --> 2,4,6-三氯嘧啶-5-胺 --> 2-氯-4-氨基-5-硝基嘧啶 --> 4,6-二氯-1H-吡唑并[3,4-C]嘧啶 --> 瑞香素-7-甲醚 --> 5-硝基-2,4,6-三氯嘧啶 --> 2,4-二氯-5-硝基-6-甲基嘧啶 --> 2-甲氧基-4-氨基-5-硝基嘧啶 --> 2-氯-4-溴嘧啶 --> 2-氯-4,5-二氨基嘧啶 --> 2,4-二氯-5 硝基嘧啶 --> 东莨菪内酯 --> 对氨基二乙基苯胺硫酸盐 --> N,N-二乙基对苯二胺盐酸盐 --> 苯基双-(对二乙氨基苯)甲烷
  • MSDS 信息:N,N-二乙基苯胺(91-66-7).msds
  • 急性毒性:吸入-大鼠 LC50: 1920 毫克/立方米/4小时; 腹注- 大鼠 LD50: 420 毫克/ 公斤
  • 外观性质:无色至黄色油状液体, 有特臭。
  • 常规方法:采用铁桶密封包装，每桶净重185kg。按有毒易燃化学品规定贮运。
  • 图谱信息:N,N-二乙基苯胺(91-66-7)核磁图( 13 CNMR) N,N-二乙基苯胺(91-66-7)质谱(MS) N,N-二乙基苯胺(91-66-7)红外图谱(IR1) N,N-二乙基苯胺(91-66-7)核磁图( 1 HNMR)
  • 储运特性:库房通风低温干燥; 与酸类、氧化剂、食品添加剂分开存放
  • 毒性分级:高毒
  • {Chemic
  • Hazard Note:Toxic

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. Solid Supported Synthesis - Specialty Synthesis
  4. Other Resins - Solid Supported Synthesis
  1. C10 - Amines
  1. C13 - Amines
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  5. C-D, Puriss p.a. - Puriss p.a.
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C8
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents

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