2,5-Dimethoxyaniline 2,5-二甲氧基苯胺

CAS 102-56-7 MFCD00008368

化学结构图

102-56-7
SMILES: COc1ccc(OC)c(N)c1

化学属性

Mol. FormulaC8H11NO2
Mol. Weight153.18
Density1.422
Flash Point130°C
TSCAYes
Melting Point78-80°C
Boiling Point140 °C at 7 mmHg
Solubility溶于水、乙醇、热里格罗因。
Stability对光敏感
Appearance 灰色片状固体。 溶于水、乙醇、热里格罗因。

别名和识别编码

Chemical Name2,5-Dimethoxyaniline
MDL NumberMFCD00008368
CAS Number102-56-7
EC Number203-040-9
Beilstein Registry Number776823
Synonym 2,5-Dimethoxyaniline {LY} 2,5-Dimethoxyaniline {} {LY} 2,5-Dimethoxyaniline {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dimethoxyaniline
PubChem Substance ID7613
Reaxys-RN776823
Chemical Name Translation2,5-二甲氧基苯胺
Wiswesser Line Notation1OR BZ DO1
LabNetwork Molecule IDLN00008686
InChIInChI=1S/C8H11NO2/c1-10-6-3-4-8(11-2)7(9)5-6/h3-5H,9H2,1-2H3
Canonical SMILESNC1=CC(OC)=CC=C1OC
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ether; 1fragment
  • {SNA} Amines, Building Blocks, C8, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 有机合成，染料中间体，杀虫剂，抗氧剂。

相关文献及参考

  • Beilstein: 13,IV,2548
  • Short: III/31a
  • Short: IV/1a
  • Short: EINECS

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSBX4375000
Packing GroupIII
UN Number 2811 UN 2811 6.1/PG 3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes 6.1 T T,Xi,Xn T;Xn
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 120 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - somnolence (general depressed activity)
   Behavioral - coma
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 4(2),30,1960

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   21,315,1972

其他信息

  • Hazard Note:Toxic/Irritant
  • 2,5-二甲氧基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1893 2,5-二甲氧基苯胺 2,5-Dimethoxyaniline 25G 182元 2014/06/02 D1893 2,5-二甲氧基苯胺 2,5-Dimethoxyaniline 500G 1060元 2014/06/02 D0623 2,5-二甲氧基苯胺 2,5-Dimethoxyaniline 25G 286元
  • 用途一:用于制备冰染染料黑色盐K的中间体及医药、杀虫剂和抗氧剂的中间体
  • 见光色变深。易溶于热水和热乙醇。溶于石油醚等大多数常规有机溶剂，不溶于冷水，水中溶解度: 4 g/L (40°C)
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物烟雾
  • 类别:有毒物品
  • 常规方法:本品一般为生产过程的中间体，不出售。
  • 用途二:该品用作染料中间体，用来生产黑色盐K（C.I.37910）。这个染料品种主要用于拼混黑色盐AMS。该品也用于生产药物、农药和抗氧剂等。
  • 方法一:对苯二酚溶解在液碱中生成对苯二酚钠盐。将对苯二酚钠盐和一氯甲烷在75-120℃、1.3-1.7MPa压力下反应生成对二甲氧基苯，再用硝酸硝化，生成2,5-二甲氧基硝基苯，用二硫化钠将其还原，即得2,5-二甲氧基苯胺。
  • Acros Organics:2,5-二甲氧基苯胺 2,5-Dimethoxyaniline, 99+%(102-56-7)
  • TCI Shanghai:2,5-二甲氧基苯胺 2,5-Dimethoxyaniline,>;97.0%(T)(102-56-7)
  • 下游产品:N-(2,5-二甲氧基苯基)-2-羟基二苯并呋喃-3-甲酰胺 --> 阳离子黄4G --> 黑色盐K --> 黑色基LS --> N-(2,5-二甲氧基苯基)-3-羟基-2-萘甲酰胺
  • 防护措施:有毒。刺激皮肤及粘膜。可引起过敏症。其毒性及防护方法参照“苯胺”。
  • Sigma Aldrich:102-56-7(sigmaaldrich)
  • 用途三:有机合成，染料中间体，杀虫剂，抗氧剂。
  • 急性毒性:口服-小鼠LD50:120 毫克/公斤; 口服-鸟LD50: 100 毫克/公斤
  • 图谱信息:2,5-二甲氧基苯胺(102-56-7)红外图谱(IR1) 2,5-二甲氧基苯胺(102-56-7)红外图谱(IR2) 2,5-二甲氧基苯胺(102-56-7)质谱(MS) 2,5-二甲氧基苯胺(102-56-7)核磁图( 1 HNMR) 2,5-二甲氧基苯胺(102-56-7)红外图谱(IR3) 2,5-二甲氧基苯胺(102-56-7)核磁图( 13 CNMR)
  • 储运特性:库房通风低温干燥
  • MOL 文件:102-56-7.mol
  • 检测方法:HPLC
  • MSDS 信息:2,5-Dimethoxyaniline(102-56-7).msds
  • F:8-10-23
  • 毒性分级:高毒
  • 上游原料:Α-球蛋白 --> 1,4-苯二酚 --> 对苯二甲醚 --> 二硫化钠
  • 存储注意事项:光敏感;氮气保护
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • Alfa Aesar:2,5-二甲氧基苯胺,99+% 2,5-Dimethoxyaniline, 99+%(102-56-7)

系列性分类

  1. C12 - Amines
  1. C8 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C7

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