N-Ethylaniline N-乙基苯胺

CAS 103-69-5 MFCD00009025

化学结构图

103-69-5
SMILES: CCNC1CCCCC1

化学属性

Mol. FormulaC8H11N
Mol. Weight121.18
Density0.963
Refractive index1.5530 to 1.5560
Flash Point85°C
TSCAYes
Boiling Point205
Melting Point-63
Vapor Density4.2 (vs air)
Vapor Pressure0.2 mmHg ( 25 °C)
Solubility不溶于水，可混溶于醇、醚。
Stability对光敏感

别名和识别编码

Chemical NameN-Ethylaniline
CAS Number103-69-5
EC Number203-135-5
Beilstein Registry Number507468
MDL NumberMFCD00009025
Synonym N-Ethylaniline {} {} {} {} {} {} { {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Merck Number3764
PubChem Substance ID87569372
Reaxys-RN507468
Chemical Name TranslationN-乙基苯胺
Wiswesser Line Notation2MR
LabNetwork Molecule IDLN00222088
InChIInChI=1S/C8H11N/c1-2-9-8-6-4-3-5-7-8/h3-7,9H,2H2,1H3
Canonical SMILESCCNC1=CC=CC=C1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C8, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 有机合成。染料中间体。

相关文献及参考

  • Short: II/27B
  • Merck:14,3764
  • Merck:14,3764 Beilstein:12,159
  • Short: III/38A

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S37 Wear suitable gloves 戴适当手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R33 Danger of cumulative effects 有累积作用的危险
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312+P330
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P307+P311
  • P308+P311
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSBX9780000
Packing GroupIII
UN Number 2272
Storage condition RT, stored under argon {LY} RT, stored under argon {} {LY} RT, stored under argon {} {} {LY} RT, stored under argon {} {} {} {LY} RT, stored under argon {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored u
Hazard statements
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 T
Hazard Class6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >1130 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0282-0429

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AGGHAR Archiv fuer Gewerbepathologie und Gewerbehygiene.  (Berlin, Ger.)
   V.1-18, 1930-61.  For publisher information, see IAEHDW.
   Volume(issue)/page/year: 15,447,1957

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AGGHAR Archiv fuer Gewerbepathologie und Gewerbehygiene.  (Berlin, Ger.)
   V.1-18, 1930-61.  For publisher information, see IAEHDW.
   Volume(issue)/page/year: 15,447,1957

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 242 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKKZAJ Yakugaku Zasshi.  Journal of Pharmacy.  (Nippon Yakugakkai, 2-12-15
   Shibuya, Shibuya-ku, Tokyo 150, Japan)  No.1-    1881-
   Volume(issue)/page/year: 97,1117,1977

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Restrict 危险品

其他信息

  • 下游产品:活性蓝BRF --> 酸性紫 17 --> 乙基苯基二硫代氨基甲酸锌 --> 活性艳红ME-2G --> 阳离子可拔白性橙 D-3R --> 阳离子红 X-GTL --> 分散大红SE-R --> 分散紫 77 --> 分散兰 257
  • 毒性分级:中毒
  • 用途三:有机合成。染料中间体。
  • Hazard Note:Toxic
  • 急性毒性:吸入- 大鼠 LC50: 1130 毫克/ 立方米/ 4小时
  • 图谱信息:N-乙基苯胺(103-69-5)核磁图( 1 HNMR) N-乙基苯胺(103-69-5)质谱(MS) N-乙基苯胺(103-69-5)红外图谱(IR1) N-乙基苯胺(103-69-5)红外图谱(IR2) N-乙基苯胺(103-69-5)核磁图( 13 CNMR)
  • 类别:有毒物品
  • N-乙基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0059 N-乙基苯胺 N-Ethylaniline 25ML 111元 2014/06/02 E0059 N-乙基苯胺 N-Ethylaniline 500ML 215元 2010/06/21 118040025 N-乙基苯胺 N-Ethylaniline 98% 2.5 KG 3264元
  • 外观性质:黄棕色透明油状液体，有苯胺气味。
  • 灭火剂:泡沫、二氧化碳、砂土、干粉
  • 方法一:1.盐酸法苯胺盐酸盐和乙醇在180℃、2.94MPa下进行反应，蒸馏出过剩的乙醇和副产物乙醚，再加入30%NaOH和对甲苯磺酰氯，用水蒸气蒸馏去除副产物二乙基苯胺，再加入硫酸，即可制得产品。2.三氯化磷法苯胺、乙醇和三氯化磷在300℃、9.84MPa下反应，将反应混合物用真空蒸馏分馏制得N-乙基苯胺。
  • 敏感性:Air & Light Sensitive
  • 蒸气密度:4.2 (vs air)
  • 上游原料:乙醇 --> 氨基苯 --> 4-甲苯磺酰氯 --> 2-乙基苯胺
  • 有苯胺样臭。强折光，暴露在空气中和光线下易变成棕色。能与乙醇、乙醚和许多有机溶剂，不溶于水。
  • 用途二:本品用于有机合成，是偶氮染料和三苯甲烷染料的重要中间休；还可用于橡胶助剂、炸药、照相材料等精细化学品的中间体。
  • TCI Shanghai:N-乙基苯胺 N-Ethylaniline,>;99.0%(GC)(103-69-5)
  • 蒸气压:0.2 mm Hg ( 25 °C)
  • 可燃性危险特性:高热分解, 明火可燃; 燃烧产生有毒氮氧化物和氯化氢烟雾
  • Alfa Aesar:N-乙基苯胺,97% N-Ethylaniline, 97%(103-69-5)
  • 用途一:用作农药及染料中间体、橡胶促进剂等
  • 储运特性:库房通风低温干燥; 与酸类、氧化剂、食品添加剂分开存放
  • Acros Organics:N-乙基苯胺 N-Ethylaniline, 98%(103-69-5)
  • Sigma Aldrich:103-69-5(sigmaaldrich)
  • F:8
  • MSDS 信息:N-乙基苯胺(103-69-5).msds
  • MOL 文件:103-69-5.mol

系列性分类

  1. C12 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds
  1. C8 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C7

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