Hexylamine 正己胺

CAS 111-26-2 MFCD00008240

化学结构图

111-26-2
SMILES: CCCCCCN

化学属性

Mol. FormulaC6H15N
Mol. Weight101
Refractive index1.4170 to 1.4200
Density0.766 g/mL at 25 °C(lit.)
Boiling Point130°C
Melting Point-23 °C (lit.)
Flash Point27°C(lit.)
TSCAYes
Solubility微溶于水，可混溶于乙醇、乙醚。
Stability对空气敏感

别名和识别编码

Chemical NameHexylamine
MDL NumberMFCD00008240
CAS Number111-26-2
Synonym HEXYLAMINE ENT 16554 NORMAL HEXYL AMINE 己胺/1-氨基己烷 己胺 1-Hexanamine n-Hexylamine aminohexane hexylamine,[liquid] 1-Amine-n-hexane MONO-N-HEXYLAMINE 1-Hexylamine 正己胺 1-氨基己烷 ETHYL-N-BUTYLAMINE hexylamine 1-Aminohexane,1-Hexanamine 1-AMINOHEXANE RARECHEM AL BW 0240 Mono-n-hexylamine 正已胺 n-C6H13NH2 1-胺己烷 1-Aminohexan 1-Aminohexane 1-Hexanamin 1-HEXYLAMINE 1-氨基正己烷 AMINE C6 Hexylamin N-HEXYLAMINE n-Hexylamin n-Hexlamin ent16554
EC Number203-851-8
Beilstein Registry Number4,188
PubChem Substance ID87570578
Chemical Name Translation正己胺
Reaxys-RN1731298
Wiswesser Line NotationZ6
LabNetwork Molecule IDLN00195679
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Amines, Building Blocks, C6, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 用作有机合成中间体及生化试剂。

相关文献及参考

  • Short: III/47
  • Beilstein:4,188
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H301+H311
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSMQ4540000
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
Signal word Danger
Packing GroupI
UN Number UN2734 2734 UN 2734 8/PG 1
Risk Statements
  • R35 Causes severe burns 会导致严重灼伤
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R10 Flammable 易燃
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R51/53
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Storage condition Flammables area 室温 Air Sensitive
Hazard Codes C C,F,Xi C,N
Hazard Class8/3
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 420 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 670 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

其他信息

  • Acros Organics:己胺/1-氨基己烷 Hexylamine, 99%(111-26-2)
  • 毒性分级:中毒
  • 上游原料:五氯化磷 --> 甲酮 --> 酮肟
  • 方法一:由甲基正已基甲酮肟用五氯化磷处理而得。将甲基正已基甲酮肟于乙醚中用五氯化磷处理，然后加水搅匀后分层。重排生成的N-乙酰正乙胺溶在乙醚中，将乙醚层分出。蒸馏回收乙醚，剩余的油状液用氢氧化钾稀溶液水解，再进行蒸馏。收集130-133℃馏分即得己胺。
  • Hazard Note:Irritant/Flammable/Corrosive/Air Sensitive
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 海关编码:29211980
  • F:34
  • 用途三:用作有机合成中间体及生化试剂。
  • 类别:易燃液体
  • 用途一:主要用于有机合成
  • MSDS 信息:正己胺(111-26-2).msds
  • 敏感性:Air Sensitive
  • 图谱信息:正己胺(111-26-2)红外图谱(IR1) 正己胺(111-26-2)质谱(MS) 正己胺(111-26-2)核磁图( 13 CNMR) 正己胺(111-26-2)核磁图( 1 HNMR) 正己胺(111-26-2)Raman光谱
  • Alfa Aesar:1-己基胺,99% 1-Hexylamine, 99%(111-26-2)
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
  • Sigma Aldrich:111-26-2(sigmaaldrich)
  • 用途二:用作有机合成中间体。
  • 急性毒性:口服- 大鼠 LD50: 670 毫克/ 公斤
  • 刺激数据:皮肤- 兔子 10 毫克/ 24小时 重度; 眼睛- 兔子 2 毫克/ 24小时 重度
  • TCI Shanghai:己胺 Hexylamine,>;99.0%(GC)(T)(111-26-2)
  • MOL 文件:111-26-2.mol
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 外观性质:无色液体。
  • FEMA:4243
  • 能与乙醇、乙醚混溶，微溶于水。有氨臭。水中溶解度:14 g/l (20°C)。
  • 正己胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A21970302 正己胺 100ml 356元 2011/08/23 K5313101 正己胺purum》98.0％ 250ml 551元 2011/04/16 H0134 己胺 Hexylamine 25ML 177元
  • 下游产品:异氰酸己酯

系列性分类

  1. C6 - Amines
  1. C10 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C11 to C38

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