4-Aminobenzenethiol 4-氨基苯硫酚

CAS 1193-02-8 MFCD00007880

化学结构图

1193-02-8
SMILES: Nc1ccc(S)cc1

化学属性

Mol. FormulaC6H7NS
Mol. Weight125.19
Density1.2395
Flash Point112.4±22.6 °C
TSCANo
Melting Point37-42°C
Boiling Point262.3±23.0 °C at 760 mmHg
Appearance 淡黄色到液体或结晶。熔点38-41℃。
Stability对热和空气敏感

别名和识别编码

Chemical Name4-Aminobenzenethiol
CAS Number1193-02-8
EC Number214-763-4
Beilstein Registry Number13(3)1221
MDL NumberMFCD00007880
Synonym 4-Aminobenzenethiol {LY} 4-Aminobenzenethiol {} {LY} 4-Aminobenzenethiol {} {} {LY} 4-Aminobenzenethiol {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Aminobenzenethiol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4
PubChem Substance ID14510
Reaxys-RN906904
Chemical Name Translation4-氨基苯硫酚
Wiswesser Line NotationZR DSH
LabNetwork Molecule IDLN00173086
InChIInChI=1S/C6H7NS/c7-5-1-3-6(8)4-2-5/h1-4,8H,7H2
Canonical SMILESSC1=CC=C(N)C=C1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiols/Mercaptans

相关文献及参考

  • Beilstein:13(3)1221

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S25 Avoid contact with eyes 避免眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
Precautionary statements
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P305+P351+P338+P310
RTECSDC0602500
Packing GroupII
UN Number UN 3263 8/PG 2 UN3263
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {}
Hazard Codes C
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 42200 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 14,111,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 42200 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 67,123,1979

其他信息

  • Alfa Aesar:4-氨基硫代苯酚,97% 4-Aminothiophenol, 97%(1193-02-8)
  • MOL 文件:1193-02-8.mol
  • MSDS 信息:4-Mercaptoaniline(1193-02-8).msds
  • 储运特性:库房通风低温干燥
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 毒性分级:高毒
  • 类别:有毒物品
  • 海关编码:29309070
  • F:10-13-23
  • 4-氨基苯硫酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A0623 4-氨基苯硫酚 4-Aminobenzenethiol 25G 1180元 2010/06/21 104680250 4-氨基苯硫酚 4-Aminothiophenol 96% 25 GR 1531元 2010/06/21 104680050 4-氨基苯硫酚 4-Aminothiophenol 96% 5 GR 483元
  • 图谱信息:4-氨基苯硫酚(1193-02-8)红外图谱(IR1) 4-氨基苯硫酚(1193-02-8)红外图谱(IR2) 4-氨基苯硫酚(1193-02-8)核磁图( 13 CNMR)
  • TCI Shanghai:4-氨基苯硫酚 4-Aminobenzenethiol,>;96.0%(GC)(1193-02-8)
  • Acros Organics:4-氨基硫酚 4-Aminothiophenol, 96%(1193-02-8)
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物和硫氧化物烟雾
  • Sigma Aldrich:1193-02-8(sigmaaldrich)
  • 敏感性:Stench
  • 用途一:用作农药、医药、染料中间体
  • Hazard Note:Corrosive/Stench
  • 急性毒性:口服-小鼠LDL0: 320 毫克/公斤; 口服-野鸟LD50: 42 毫克/公斤
  • 4-氨基苯硫酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0623 4-氨基苯硫酚 4-Aminobenzenethiol 25G 637元 2010/06/21 104680250 4-氨基苯硫酚 4-Aminothiophenol 96% 25 GR 1531元 2010/06/21 104680050 4-氨基苯硫酚 4-Aminothiophenol 96% 5 GR 483元
  • 存储注意事项:空气敏感

系列性分类


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