3-Morpholinopropan-1-amine 4-吗啉基丙胺

CAS 123-00-2 MFCD00006184

化学结构图

123-00-2
SMILES: NCCCN1CCOCC1

化学属性

Mol. FormulaC7H16N2O
Mol. Weight144.21
Density0.987 g/mL at 25 °C(lit.)
Refractive index1.4760 to 1.4780
Boiling Point224°C at 760 mmHg
Melting Point-15°C
Flash Point98.89°C
TSCAYes
Solubility可溶

别名和识别编码

Chemical Name3-Morpholinopropan-1-amine
CAS Number123-00-2
Alfabeta NameMORPHOLINYLPROPANAMINE 341()----
MDL NumberMFCD00006184
Synonym 3-Morpholinopropan-1-amine {LY} 3-Morpholinopropan-1-amine {} {LY} 3-Morpholinopropan-1-amine {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Morpholinopropan-1-amine {} {} {} {} {}
EC Number204-590-2
Beilstein Registry Number27(3/4)411
PubChem Substance ID87562044
Reaxys-RN105104
Chemical Name Translation4-吗啉基丙胺
Wiswesser Line NotationT6N DOTJ A3Z
LabNetwork Molecule IDLN00132650
InChIInChI=1S/C7H16N2O/c8-2-1-3-9-4-6-10-7-5-9/h1-8H2
Canonical SMILESNCCCN1CCOCC1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; ether; 1fragment
  • {SNA} Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines

产品应用

  • 用于合成纤维。

相关文献及参考

  • Beilstein:27(3/4)411
  • Short: EINECS
  • Short: III/38B

安全信息

Warnings IRRITANT
Signal word Danger
GHS Symbol
WGK Germany2
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P303+P361+P353
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P304+P340+P310
  • P301+P330+P331+P310
  • P305+P351+P338+P310
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H312 Harmful in contact with skin 皮肤接触有害
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSQD7700000
Packing GroupIII
UN Number 2735 UN2735 UN 2735 8/PG 2
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from
Hazard Codes C C,Xi
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3560 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 3/25/1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1230 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

其他信息

  • MOL 文件:123-00-2.mol
  • 储运特性:库房通风低温干燥
  • TCI Shanghai:4-吗啉丙胺 N-(3-Aminopropyl)morpholine,>;99.0%(GC)(123-00-2)
  • 毒性分级:中毒
  • 刺激数据:皮肤-兔子 10 毫克/24小时 重度; 眼睛-兔子 0.25 毫克/24小时 重度
  • 可燃性危险特性:较易燃;燃烧产生有毒氮氧化物烟雾
  • 灭火剂:干粉、泡沫、砂土, 二氧化碳, 雾状水
  • 可溶于水、乙醇、苯、己烷和石油醚。
  • 类别:易燃液体
  • Sigma Aldrich:123-00-2(sigmaaldrich)
  • Alfa Aesar:4-3-氨丙基吗啉,98% 3-(4-Morpholinyl)propylamine, 98%(123-00-2)
  • 急性毒性:口服-大鼠LD50: 3560 毫克/公斤; 皮肤-兔子LD50: 1230 毫克/公斤
  • 图谱信息:N-(3-氨丙基)吗啉(123-00-2)质谱(MS) N-(3-氨丙基)吗啉(123-00-2)核磁图( 1 HNMR) N-(3-氨丙基)吗啉(123-00-2)核磁图( 13 CNMR) N-(3-氨丙基)吗啉(123-00-2)红外图谱(IR1)
  • N-(3-氨丙基)吗啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0409 N-(3-氨丙基)吗啉 N-(3-Aminopropyl)morpholine 25ML 180元 2014/06/02 A0409 N-(3-氨丙基)吗啉 N-(3-Aminopropyl)morpholine 500ML 1260元 2010/06/21 153870010 N-(3-氨丙基)吗啉 N-(3-Aminopropyl)morpholine 98% 1 KG 3322元
  • 用途一:用于合成纤维。
  • F:10-34
  • 检测方法:GC,NMR
  • MSDS 信息:N-氨丙基吗啉(123-00-2).msds
  • 外观性质:无色澄清液体。
  • Acros Organics:N-(3-氨丙基)吗啉 N-(3-Aminopropyl)morpholine, 98%(123-00-2)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Indazoles 吲唑
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Isoxazoles 异恶唑
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Morpholines/Thiomorpholines 吗啉/硫吗啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Morpholines/Thiomorpholines 吗啉/硫吗啉
  5. C4 to C10 - Morpholines/Thiomorpholines

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