Rhodium(II) Acetate Dimer 乙酸铑(II)二聚体
CAS 15956-28-2 MFCD00003538
化学结构图
SMILES: CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O
化学属性
| Mol. Formula | Rh2(OOCCH3)4 |
|---|---|
| Mol. Weight | 441.99 |
| Melting Point | 205 °C |
| TSCA | No |
| Solubility | Slightly soluble in ethanol |
| Density | 1.422 |
| Appearance | greenish-black xtl. |
别名和识别编码
| Chemical Name | Rhodium(II) Acetate Dimer |
|---|---|
| Synonym | Dirhodium tetraacetate {LY} Dirhodium tetraacetate {} {LY} Dirhodium tetraacetate {} {} {LY} Dirhodium tetraacetate {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} { |
| MDL Number | MFCD00003538 |
| PubChem Substance ID | 24852229 |
| CAS Number | 15956-28-2 |
| EC Number | 240-084-8 |
| Reaxys-RN | 14201302 |
| Beilstein Registry Number | 14201302 |
| Chemical Name Translation | 乙酸铑(II)二聚体 |
| Canonical SMILES | O1=C([O-][Rh+2]234O=C([O-][Rh+2]14(O=C([O-]2)C)[O-]C(=O3)C)C)C |
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分类
- {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Rhodium, Solution Deposition Precursors
- {SNA} C-H Activation, Cata
- Materials Science, Micro/NanoElectronics, Rhodium, Solution Deposition Precursors
- {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Essential Chemicals, Metal and Ceramic Science, Micro/NanoElectronics, Research Essentials, Rhodium, Rhodium Salts, Salts, Solution Deposition Precursors, 材料科学
产品应用
- 烯烃的环丙烷化，同源催化剂，高效催化剂，用于形成叶立德。
相关文献及参考
- Catalyst for various cyclization reactions involving ɑ-diazo carbonyl groups. Promotes the formation of macrocyclic lactones via intramolecular cyclopropanation and carbon-hydrogen insertion: J. Am. Chem. Soc., 117, 7181 (1995). For a brief feature on uses of the reagent in synthesis, see: Synlett, 3169 (2005).
- Sugimura, T.; Mori, A. et. al. Tetrahedron Asymmetry 14 , 881, (2003)
- Zhu, S.; Liao, Y.; Zhu, S. Org. Lett. 6 , 377, (2004) 摘要
- Beil. 2 ,124
安全信息
- S15 Keep away from heat 远离热源；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
TYPE OF TEST : LD10 - Lethal Dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 115 mg/kg TOXIC EFFECTS : Tumorigenic - active as anti-cancer agent REFERENCE : JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 20,943,1977
其他信息
- 溶于水。微溶于乙醇。
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