Phosphonium, (3-​carboxypropyl)​triphenyl-​, bromide (1:1) (3-丙羧基)三苯基溴化膦

CAS 17857-14-6 MFCD00274196

化学结构图

17857-14-6
SMILES: [Br-].OC(=O)CCC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC22H22BrO2P
Mol. Weight429
Melting Point246.0 to 250.0 deg-C
TSCANo
Stability易吸潮

别名和识别编码

Chemical NamePhosphonium, (3-​carboxypropyl)​triphenyl-​, bromide (1:1)
Synonym
MDL NumberMFCD00274196
PubChem Substance ID87566628
CAS Number17857-14-6
Reaxys-RN4173599
EC Number000-000-0
Beilstein Registry Number4173599
Chemical Name Translation(3-丙羧基)三苯基溴化膦
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Luo, Y.; et al. Bioorg. Med. Chem. Lett. 21 , 4844, (2011)
  • 2. Zhang, Y.-K.; et al. Bioorg. Med. Chem. Lett. 21 , 644, (2011)
  • 3. Wube, A. A.; et al. Bioorg. Med. Chem. 19 , 567, (2011)
  • 4. Robinson, A.; Aggarwal, V. K. Angew. Chem. Int. Ed. Engl. 49 , 6673, (2010)
  • 5. Dylag, M.; et al. Med. Mycol 48 , 373, (2010)
  • 6. Zhang, Y.-N.; et al. Bioorg. Med. Chem. 16 , 8697, (2008)
  • 7. Fox, M. E.; et al. J. Org. Chem. 70 , 1227, (2005)
  • FT-IR 2 (2), 3337:C

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Hygroscopic

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. METI - MZ - M
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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