2-Amino-5-nitropyridine, 99% 2-氨基-5-硝基吡啶

CAS 4214-76-0 MFCD00006325

化学结构图

4214-76-0
SMILES: Nc1ccc([N+](=O)[O-])cn1

化学属性

Mol. FormulaC5H5N3O2
Mol. Weight139.11
Density1.422
Flash Point224°(435°F)
TSCAYes
Melting Point127-131°C
Appearance 淡黄色粉末
Boiling Point293.8°C at 760 mmHg

别名和识别编码

Chemical Name2-Amino-5-nitropyridine, 99%
CAS Number4214-76-0
Alfabeta NameAMINONITROPYRIDINE 25---
MDL NumberMFCD00006325
Synonym 5-Nitropyridin-2-amine {LY} 5-Nitropyridin-2-amine {} {LY} 5-Nitropyridin-2-amine {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitropyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number224-145-6
Beilstein Registry Number22(1)631
PubChem Substance ID77888
Chemical Name Translation2-氨基-5-硝基吡啶
Reaxys-RN120353
InChIKeyUGSBCCAHDVCHGI-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009010
InChIInChI=1S/C5H5N3O2/c6-5-2-1-4(3-7-5)8(9)10/h1-3H,(H2,6,7)
Canonical SMILESO=[N+](C1=CN=C(N)C=C1)[O-]
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分类

  • Bases & Related Reagents
  • {SNA} Building Blocks, C5, Chemical Synthesis, Heterocyclic Building Blocks, NLO Chromophores and Intermediates, Non-Linear Optical (NLO) Materials, Organic and Printed Electronics, Photonic and Optical Materials, Pyridines, 材料科学
  • {SNA} Building Blocks, C5, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • Nucleotides
  • {SNA} Building Blocks, C5, Chemical Synthesis, Heterocyclic Building Blocks, Materials Science, NLO Chromophores and Intermediates, Non-Linear Optical (NLO) Materials, Organic and Printed Electronics, Photonic and Optical Materials, Pyridines

相关文献及参考

  • Francotte, P., et al.: Bioorg. Med. Chem., 16, 9948 (2008),

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi

其他信息

  • 图谱信息:2-氨基-5-硝基吡啶(4214-76-0)质谱(MS) 2-氨基-5-硝基吡啶(4214-76-0)红外图谱(IR2) 2-氨基-5-硝基吡啶(4214-76-0)红外图谱(IR1)
  • 上游原料:硝酸 --> 2-氨基吡啶 --> 色片
  • Sigma Aldrich:4214-76-0(sigmaaldrich)
  • 下游产品:2-氯-5-硝基吡啶 --> 2-氨基-5-氟吡啶 --> 2-氨基-3-溴-5-硝基吡啶
  • 方法一:由2-氨基吡啶硝化而得。在温度50℃下,将2-氨基吡啶加到浓硫酸中,再滴加发烟硝酸,温度不超过50℃。45℃保温2h,室温条件下搅拌4h。反应液倾入碎冰中,5℃以下加氨水调节至pH6,析出晶体。过滤,干燥。用水重结晶,得淡黄色片晶,收率75%
  • Hazard Note:Irritant
  • TCI Shanghai:2-氨基-5-硝基吡啶 2-Amino-5-nitropyridine,>;98.0%(T)(4214-76-0)
  • 2-氨基-5-硝基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0794 2-氨基-5-硝基吡啶 2-Amino-5-nitropyridine 250G 4240元 2014/06/02 A0794 2-氨基-5-硝基吡啶 2-Amino-5-nitropyridine 25G 700元 2010/06/21 104231000 2-氨基-5-硝基吡啶 2-Amino-5-nitropyridine 99% 100 GR 2088元
  • MSDS 信息:2-Amino-5-nitropyridine(4214-76-0).msds
  • 海关编码:29333999
  • Alfa Aesar:2-氨基-5-硝基吡啶,98% 2-Amino-5-nitropyridine, 98%(4214-76-0)
  • 用途一:作医药中间体。
  • 检测方法:HPLC,NMR
  • MOL 文件:4214-76-0.mol
  • Acros Organics:2-氨基-5-硝基吡啶 2-Amino-5-nitropyridine, 99%(4214-76-0)
  • 敏感性:Light Sensitive

系列性分类


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