MERCURIC OXIDE, RED 氧化铯*HSYHG

CAS 21908-53-2 MFCD00011045

化学结构图

21908-53-2
SMILES: O=[Hg]

化学属性

Mol. FormulaHgO
Mol. Weight216.59
Melting Point500 °C (dec.)(lit.)
Density11.14
TSCAYes

别名和识别编码

Chemical NameMERCURIC OXIDE, RED
Synonym Santar M 三仙丹 Yellow precipitate Quecksilber(II)-oxid Quecksilberoxid Mercury(II) oxide, Yellow Santar Mercury(II)oxide Mercuric oxide (HgO) Mercury Monoxide red Mercury monoxide Mercuric oxide Mercury(II) oxide, red Mercury oxide (HgO) Mercuric Oxide Yellow Gelbes Praezipitat Mercury(II) oxide Quecksilber(II)-oxid, rot mercury (II) oxide Mercury(II) oxide Red Yellow mercuric oxide 氧化汞(II) Red mercuric oxide Mercuric oxide red Mercuric Oxide, Yellow Mercury(2+) oxide Mercury (II) oxide Red Mercury(II)oxide, yellow Quecksilber(II)-oxid rot BG I Mercury(II) Oxide, Red, Quecksilber(II)-oxid, gelb Mercury (II) oxide Yellow Quecksilber(II)oxid Mercury(II) oxide Yellow Oxyde de mercure Red oxide of mercury Mercuric oxide, red Yellow Mercuric Oxide C.I. 77760 Quecksilber(II)-oxid gelb Quecksilber(II)-oxid rot
CAS Number21908-53-2
PubChem Substance ID24856705
EC Number244-654-7
MDL NumberMFCD00011045
Merck Number14,5883
Chemical Name Translation氧化铯*HSYHG
Wiswesser Line NotationHG O
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Mercury, Metal and Ceramic Science, Oxides, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Hg, Mercury, Metal and Ceramic Science, Oxides, Ultra-High Purity Materials, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Hg, Materials Science, Mercury, Metal and Ceramic Science, Oxides, Ultra-High Purity Materials
  • {uni_hamburg} no charge; 2fragments; ionic

相关文献及参考

  • Merck 14 ,5882 / Merck 14 ,5883
  • Fieser 1 ,655 / Fieser 2 ,267 / Fieser 4 ,323 / Fieser 5 ,428 / Fieser 6 ,360 / Fieser 7 ,224 / Fieser 8 ,316 / Fieser 9 ,293 / Fieser 12 ,305
  • Corp MSDS 1 (2), 2219:B / RegBook 1 (3), 3281:E / Sax 6 , 1747
  • Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31a Year: 1993 Keyword: NQR ISBN: 3-540-55146-8 ISBN: 978-3-540-55146-1 Internet Resource: DOI:10.1007/b43999 RefComment: VIII, 437 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data
  • Literature references should be checked to see whether the red form or the more finely-divided yellow form of the oxide is specified, although this may not be stated.
  • Mercury(II) salts can be used in place of the more expensive silver salts in a modification of the Hunsdiecker conversion of carboxylic acids to alkyl bromides. Reviews: Chem. Rev., 56, 219 (1956); Org. React., 9, 341 (1957). For the mercury(II) oxide method, see: Org. Synth. Coll., 5, 126 (1955); 6, 179 (1988):
  • Reagent for the oxidation of hydrazones to diazoalkanes. For examples, see: Org. Synth. Coll., 3, 351 (1955); 6, 392 (1988).

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T+,N T+;N
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSOW8750000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310+P330
  • P304+P340+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P310
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
Signal word Danger
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
UN Number 1641 UN1641
Risk Statements
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
  • R50/53
  • R33 Danger of cumulative effects 有累积作用的危险
Packing GroupII
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 315 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intramuscular
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 22 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the
   National Cancer Institute by The Institute of Chemical Biology, University
   of San Francisco.  (San Francisco, CA 94117)  Volume(issue)/page/year:
   PH43-64-886

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB214-270

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 16 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 1130

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 34 mg/kg
SEX/DURATION            : female 10 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   APTOD9 Abstracts of Papers, Society of Toxicology.  Annual Meetings.
   (Academic Press, Inc., 1 E. First St., Duluth, MN 55802)
   Volume(issue)/page/year: 19,A126,1980

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 225 mg/kg
SEX/DURATION            : female 4-12 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - other developmental
   abnormalities
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 26(1),46A,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 10800 ug/kg
SEX/DURATION            : female 5 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 10800 ug/kg
SEX/DURATION            : female 5 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - eye/ear
REFERENCE :
   PWPSA8 Proceedings of the Western Pharmacology Society.  (Univ. of
   California Dept. of Pharmacology, Los Angeles, CA 90024)  V.1-    1958-
   Volume(issue)/page/year: 15,52,1972

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