(2S)-but-3-yn-2-ol (S)-(-)-3-丁炔-2-醇

CAS 2914-69-4 MFCD00190166

化学结构图

2914-69-4
SMILES: C#C[C@H](C)O

化学属性

Mol. FormulaC4H6O
Mol. Weight70.09
Refractive index1.4240 to 1.4280
Boiling Point108-111 °C at 760 mmHg
Density0.883
Flash Point26°C(lit.)
TSCANo
Melting Point-22.07 °C

别名和识别编码

Chemical Name(S)-(-)-1-Butyn-3-Ol
CAS Number2914-69-4
PubChem Substance ID6995470
Beilstein Registry Number4652597
MDL NumberMFCD00190166
Reaxys-RN2321757
EC Number250-023-7
Synonym (S)-(-)-3-Butyn-2-ol {LY} (S)-(-)-3-Butyn-2-ol {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-(-)-3-Butyn-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-(-)-3-Bu
Chemical Name Translation(S)-(-)-3-丁炔-2-醇
LabNetwork Molecule IDLN01740739
InChIInChI=1S/C4H6O/c1-3-4(2)5/h1,4-5H,2H3/t4-/m0/s1
Canonical SMILESC[C@@H](C#C)O
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分类

  • {SNA} Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks

相关文献及参考

  • 1. Macromolecules 40 , 1864, (2007)
  • Beil. 1 ,IV,2218

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H300 Fatal if swallowed 吞食致命
  • H301 Toxic if swallowed 吞食有毒
  • H310 Fatal in contact with skin 皮肤接触致命
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H330 Fatal if inhaled 吸入致命
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F;T+ F,T+
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P310+P330
  • P301+P316
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P333+P317
  • P337+P313
  • P337+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number 2929
Risk Statements
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupII
Hazard Class6.1/3
Storage condition 2-8°C {LY} 2-8°C Poison room {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • Acros Organics:(S)-(-)-3-Butyn-2-ol, 98% ee, 95%(2914-69-4)
  • TCI Shanghai:(S)-(-)-3-丁炔-2-醇 (S)-(-)-3-Butyn-2-ol,>;98.0%(GC)(2914-69-4)
  • F:10-23
  • (S)-(-)-3-丁炔-2-醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2910 (S)-(-)-3-丁炔-2-醇 (S)-(-)-3-Butyn-2-ol 1G 899元 2010/06/21 362410050 (S)-(-)-3-丁炔-2-醇 (S)-(-)-3-Butyn-2-ol 95%, 98% ee 5 GR 8417元 2010/06/21 362410010 (S)-(-)-3-丁炔-2-醇 (S)-(-)-3-Butyn-2-ol 95%, 98% ee 1 GR 2441元
  • Sigma Aldrich:2914-69-4(sigmaaldrich)
  • 比旋光度:-45 ° (neat)
  • Alfa Aesar:(S)-(-)-3-丁炔-2-醇,99% (S)-(-)-3-Butyn-2-ol, 99%(2914-69-4)
  • MOL 文件:2914-69-4.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Alcohols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Acetylenes 炔烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Acid Halides 酰卤