Lithium Trifluoromethanesulfonate 三氟甲磺酸锂

CAS 33454-82-9 MFCD00013227

化学结构图

33454-82-9
SMILES: O=S(=O)([O-])C(F)(F)F.[Li+]

化学属性

Mol. FormulaCF3LiO3S
Mol. Weight156.00
Melting Point>300
TSCAYes
Density1.876
Stability对湿度敏感
Appearance white pwdr.

别名和识别编码

Chemical NameLithium Trifluoromethanesulfonate
Synonym LiTf LiTf 三氟甲基磺酸锂 三氟甲烷磺酸 锂盐 LiTf;三氟甲基磺酸锂;三氟甲烷磺酸 锂盐 Lithium triflate Lithium-Trifluormethansulfonat Lithiumtriflat (Lithiumtrifluormethansulfonat) Lithiumtrifluormethansulfonat Methanesulfonic acid, trifluoro-, lithium salt Trifluoromethanesulfonic Acid Lithium Salt, Lithium Triflate Trifluoromethanesulfonic acid, lithium salt Trifluoromethanesulphonic acid lithium salt lithium trifluoromethanesulfonate lithium trifluoromethanesulphonate 三氟甲基磺酸锂 三氟甲基磺酸锂 三氟甲烷磺酸 锂盐 三氟甲基磺酸锂;三氟甲烷磺酸;锂盐 三氟甲磺酸锂
MDL NumberMFCD00013227
PubChem Substance ID87577307
Beilstein Registry Number4301818
EC Number251-528-5
CAS Number33454-82-9
Chemical Name Translation三氟甲磺酸锂
Reaxys-RN4301818
LabNetwork Molecule IDLN00220303
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分类

  • {uni_hamburg} no charge; 2fragments
  • {SNA} Chemical Synthesis, Inorganic Salts,
  • {SNA} Alternative
  • {SNA} Chemical Synthesis, Essential Chemicals, Inorganic Salts, Lithium, Lithium Salts, Metal and Ceramic Science, Research Essentials, Salts, Synthetic Reagents, 材料科学
  • {SNA} Alternative Energy, Ch

相关文献及参考

  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Catalyzes the aminolysis of epoxides in acetonitrile solution to give high yields of ß-amino alcohols, providing a safer substitute for Li perchlorate: Tetrahedron Lett., 37, 7715 (1996). Effective replacement for Li perchlorate as catalyst for Diels-Alder reactions: Synlett, 877 (2000).
  • Efficient catalyst for chemoselective dithioacetalization of aldehydes, e.g. with 1,3-propanedithiol, under neutral, solvent-free conditions: Tetrahedron Lett., 40, 4055 (1999).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture Sensitive 充氩保存
Hazard Codes Xi

系列性分类