Bicyclo[2.2.1]hept-2-ene 降冰片烯

CAS 498-66-8 MFCD00082304

化学结构图

498-66-8
SMILES: C1=C[C@@H]2CC[C@H]1C2

化学属性

Mol. FormulaC7H10
Mol. Weight94.16
Flash Point-8°C
TSCAYes
Melting Point44-46°C
Boiling Point96°C at 760 mmHg
Density0.955

别名和识别编码

Chemical NameBicyclo[2.2.1]hept-2-ene
MDL NumberMFCD00082304
Synonym Bicyclo[2.2.1]hept-2-ene {LY} Bicyclo[2.2.1]hept-2-ene {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bicyclo[2.2.1]hept-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number207-866-0
CAS Number498-66-8
Beilstein Registry Number1098544
PubChem Substance ID10352
Chemical Name Translation降冰片烯
Reaxys-RN1098544
Wiswesser Line NotationL55 A CUTJ
LabNetwork Molecule IDLN01743325
InChIInChI=1S/C7H10/c1-2-7-4-3-6(1)5-7/h1-2,6-7H,3-5H2
Canonical SMILESC1(C2)C=CC2CC1
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分类

  • {uni_hamburg} no charge; carbocycle; alicycle; fused rings; 5ring; 6ring; racemate; 1fragment
  • {SNA} Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Organic Building Blocks
  • {SNA} Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Materials Science, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science
  • {SNA} Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science, 材料科学

相关文献及参考

  • Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/10a Title: Structure Data of Organic Crystals: C ... C 15 Author

安全信息

RTECSRB7900000
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S29 Do not empty into drains 不要排入下水道;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
UN Number 1325 UN1325
Risk Statements
  • R11 Highly flammable 非常易燃
Signal word Danger
GHS Symbol
WGK Germany1
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H228 Flammable solid 易燃固体
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupII
Hazard Codes 4.1 F
Hazard Class4.1
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >5 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 11300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

其他信息

  • MOL 文件:498-66-8.mol
  • F:13
  • Acros Organics:2-崁烯 Norbornylene, stabilized, 99%(498-66-8)
  • 下游产品:乙叉降冰生烯 --> 甲基丙烯酸多环降冰片烯酸和甲基丙烯酸甲酯共聚物 --> 乙丙三元胶磺酸型离聚物作为缓释化肥包膜材料
  • Sigma Aldrich:498-66-8(sigmaaldrich)
  • 降冰片烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0166 2-降冰片烯 2-Norbornene 500G 875元 2014/06/02 N0166 2-降冰片烯 2-Norbornene 25G 104元 2010/06/21 129245000 降冰片烯 Norbornylene 99%, stabilized 500 GR 1006元
  • TCI Shanghai:降冰片烯 2-Norbornene,>;99.0%(GC)(498-66-8)
  • 图谱信息:降冰片烯(498-66-8)质谱(MS) 降冰片烯(498-66-8)核磁图( 13 CNMR) 降冰片烯(498-66-8)红外图谱(IR1)
  • Alfa Aesar:降冰片烯,99% Norbornene, 99%(498-66-8)
  • 不溶于水,溶于苯和甲苯。

系列性分类