D-Tyrosine D-酪氨酸

CAS 556-02-5 MFCD00063073

化学结构图

556-02-5
SMILES: N[C@H](Cc1ccc(O)cc1)C(=O)O

化学属性

Mol. FormulaC9H11NO3
Mol. Weight181.19
Density1.333
Melting Point>300°C
TSCAYes
Solubility可溶
Appearance 22 D +10.3°(0.5-2.0 mg/ml，1 mol/L HCl)。 白色针状结晶，无臭，味苦；溶于碱溶液和稀酸，难溶于水，不溶于丙酮、乙醇和乙醚；分解点为310-314℃；比旋光度[α]
Refractive index11.2 ° (C=5, 1mol/L HCl)
Boiling Point385.2°C at 760 mmHg

别名和识别编码

Chemical NameD-Tyrosine
MDL NumberMFCD00063073
CAS Number556-02-5
EC Number209-112-6
Beilstein Registry Number14,605
Synonym D-Tyrosine {LY} D-Tyrosine {} {LY} D-Tyrosine {} {} {LY} D-Tyrosine {} {} {} {LY} D-Tyrosine {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Tyrosine
Merck Number9839
PubChem Substance ID87576929
Reaxys-RN2212157
Chemical Name TranslationD-酪氨酸
LabNetwork Molecule IDLN00008738
InChIKeyOUYCCCASQSFEME-MRVPVSSYSA-N
InChIInChI=1S/C9H11NO3/c10-8(9(12)13)5-6-1-3-7(11)4-2-6/h1-4,8,11H,5,10H2,(H,12,13)/t8-/m1/s1
Canonical SMILESN[C@H](CC1=CC=C(O)C=C1)C(O)=O
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分类

  • {SNA} Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Dopaminergics, Neuroscience, Neurotransmission, Neurotransmitters, Other Dopaminergics, Peptide Chemistry, Tyrosine, 细胞信号转导和神经科学, 细胞生物学
  • {Chemicalbook} 生物化学品: 生化试剂: 氨基酸及其衍生物
  • {SNA} Amino Acid Derivatives, Bioactive Small Molecules, Cell Biology, Cell Signaling and Neuroscience, Chemical Biology, Chemical Synthesis, Dopaminergics, Neuroscience, Neurotransmission, Neurotransmitters, Others, Peptide Chemistry,

产品应用

  • 用作生化试剂，也可作为研究蛋白质结构和动力学的探针。

相关文献及参考

  • [2]. Cong Yu, et al. Inhibition of Biofilm Formation by D-tyrosine: Effect of Bacterial Type and D-tyrosine Concentration. Water Res. 2016 Apr 1;92:173-9.
  • Merck:14,9839
  • Merck:14,9839 Beilstein:14,605
  • [1]. Jisu Park, et al. D-tyrosine Negatively Regulates Melanin Synthesis by Competitively Inhibiting Tyrosinase Activity. Pigment Cell Melanoma Res. 2018 May;31(3):374-383.
  • [1]. Jisu Park, et al. D-tyrosine Negatively Regulates Melanin Synthesis by Competitively Inhibiting Tyrosinase Activity. Pigment Cell Melanoma Res. 2018 May;31(3):374-383.
  • [2]. Cong Yu, et al. Inhibition of Biofilm Formation by D-tyrosine: Effect of Bacterial Type and D-tyrosine Concentration. Water Res. 2016 Apr 1;92:173-9.

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C Store at RT. {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C

其他信息

  • Alfa Aesar:D-酪胺酸,98% D-Tyrosine, 99%(556-02-5)
  • 参考质量标准:含量不少于98.0%；比旋光度[α] 20 D +9.3°-+11.3°；纸层析合格。
  • Acros Organics:D-酪氨酸 D-Tyrosine, 98%(556-02-5)
  • TCI Shanghai:D-酪氨酸 D-Tyrosine,>;98.0%(T)(556-02-5)
  • 用途一:用于生化研究。
  • MSDS 信息:D-Tyrosine(556-02-5).msds
  • Sigma Aldrich:556-02-5(sigmaaldrich)
  • 它与L-酪氨酸是光学异构体，系非蛋白质氨基酸。不溶于一般中性有机溶剂如无水乙醇、乙醚、丙酮等。
  • 用途二:用作生化试剂，也可作为研究蛋白质结构和动力学的探针。
  • 比旋光度:11.3 ° (c=5, 1N HCl)
  • MOL 文件:556-02-5.mol
  • D-酪氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K9384001 D-酪氨酸;D-β-对羟基苯基丙氨酸;D-苯酚氨基丙酸;D-β-对羟苯基-α-氨基丙酸;D-干酪氨基酸 1g 722元 2011/04/16 T1141 D-酪氨酸 D-Tyrosine 5G 549元 2011/04/16 T1141 D-酪氨酸 D-Tyrosine 25G 1810元
  • 方法一:以DL-酪氨酸为原料，与氯乙酰氯进行酰化反应，过滤后浓缩，用沸丙酮萃取、石油醚重结晶，盐酸酸化后再次重结晶得产品。
  • 上游原料:氯乙酰氯 --> DL-酪氨酸

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Bioactive Small Molecules - Cell Biology
  4. T - Bioactive Small Molecules
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Tyrosine - Amino Acid Derivatives
  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Cell Signaling and Neuroscience - Cell Biology
  4. Neuroscience - Cell Signaling and Neuroscience
  5. Neurotransmission - Neuroscience
  6. Neurotransmitters - Neurotransmission
  7. Dopaminergics - Neurotransmitters
  8. Others - Dopaminergics
  1. Medical Research Areas
  2. Metabolism
  3. Tyrosinase  (酪氨酸酶)

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