(R)-(-)-2-Amino-1-Butanol (R)-(-)-2-氨基-1-丁醇

CAS 5856-63-3 MFCD00064419

化学结构图

5856-63-3
SMILES: CCC(N)CO

化学属性

Mol. FormulaC4H11NO
Mol. Weight89.14
Refractive index1.4490 to 1.4540
Boiling Point177.2°C at 760 mmHg
Density0.943
Melting Point-2°C
Flash Point95°C
TSCAYes
Solubility与水混溶,溶于醇、醚。
Stability对空气敏感,易吸潮
pH:A

别名和识别编码

Chemical Name(R)-(-)-2-Amino-1-Butanol
CAS Number5856-63-3
PubChem Substance ID87562472
EC Number227-476-4
Beilstein Registry Number1718929
MDL NumberMFCD00064419
Synonym (R)-2-Aminobutan-1-ol {LY} (R)-2-Aminobutan-1-ol {} {LY} (R)-2-Aminobutan-1-ol {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Aminobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Aminobuta
Chemical Name Translation(R)-(-)-2-氨基-1-丁醇
Reaxys-RN1718929
Canonical SMILESCC[C@@H](N)CO
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分类

  • {SNA} Amino Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks

相关文献及参考

  • Beil. 4 ,IV,1705 / Beil. 4 ,291
  • Aldrich MSDS 1 , 65:D / Corp MSDS 1 (1), 147:A / Corp MSDS 1 (1), 147:B / FT-IR 1 (1), 338:A / FT-IR 2 (1), 528:D / FT-IR 1 (1), 337:C / FT-NMR 1 (1), 539:A / FT-NMR 1 (1), 538:B / IR-Spectra (3), 198:F / IR-Spectra (2), 179:B / RegBook 1 (1), 363:F / RegBook 1 (1), 363:D / Sax 6 , 203 / Structure Index 1 , 50:D:9 / Structure Index 1 , 50:B:9 / Vapor Phase 3 , 427:C
  • For an extensive review of the use of 1,2-amino alcohols as chiral auxiliaries in asymmetric synthesis, see: Chem. Rev., 96, 835 (1996).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupIII
UN Number 2735
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive & Hygroscopic {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C,
Hazard Class8

系列性分类


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