2,6-Dibromophenol 2,6-二溴苯酚

CAS 608-33-3 MFCD00002152

化学结构图

608-33-3
SMILES: Oc1c(Br)cccc1Br

化学属性

Mol. FormulaC6H4Br2O
Mol. Weight251.90
Boiling Point256.6°C at 760 mmHg
Melting Point53-56°C
Density1.422
TSCAYes
Flash Point255-256°C
Appearance 白色针状结晶体。熔点56-57℃，沸点255-256℃（98.4kPa），162℃（2.8kPa）。溶于乙醇、乙醚、苯、二硫化碳、热水和碱溶液。易吸水，能升华。

别名和识别编码

Chemical Name2,6-Dibromophenol
CAS Number608-33-3
Alfabeta NameDIBROMOPHENOL 26-,
MDL NumberMFCD00002152
PubChem Substance ID87559118
EC Number210-161-0
Beilstein Registry Number2043614
Reaxys-RN2043614
Synonym 2,6-Dibromophenol {LY} 2,6-Dibromophenol {} {LY} 2,6-Dibromophenol {} {} {LY} 2,6-Dibromophenol {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromophenol
Chemical Name Translation2,6-二溴苯酚
LabNetwork Molecule IDLN00173695
Canonical SMILESOC1=C(Br)C=CC=C1Br
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分类

  • Bioactive Small Molecules, Building Bloc
  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Bioactive Small Molecules, Bromo, Cell Biology, Chemical Class, Chromatography, D, D-DIF, DIA - DIC, Environmental Standards, Halogenated, Volatiles/ Semivolatiles
  • {SNA} Bioactive Small Molecules, Building Blocks, C6 to C8, Chemical Synthesis,

产品应用

  • 2,6-Dibromophenol has been used in the preparation of 2-(2,6-dibromophenoxy)ethylbromide

相关文献及参考

  • Beil. 6 ,IV,1064
  • Aldrich MSDS 1 , 586:D / Corp MSDS 1 (1), 1086:D / FT-IR 1 (1), 1083:C / FT-IR 2 (2), 1852:D / FT-NMR 1 (2), 261:A / RegBook 1 (1), 1275:G / Structure Index 1 , 194:C:2 / Vapor Phase 3 , 1016:D
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302+H312+H332
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes 6.1 Xn Xn,Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P301+P312
  • P302+P352
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 2811 UN 2811 6.1/PG 3
Packing GroupIII
Hazard Class6.1
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • TCI Shanghai:2,6-二溴苯酚 2,6-Dibromophenol,>;95.0%(GC)(608-33-3)
  • 上游原料:亚硫酸氢钠
  • Sigma Aldrich:608-33-3(sigmaaldrich)
  • 方法一:由苯酚经磺化、溴化、水解而得。先将98%硫酸于44-50℃滴加到苯酚中，加毕升温至100℃，保温3h，加入冰水溶解固体，然后在20℃滴加溴，并通入氯气，在搅拌下加入亚硫酸氢钠反应30min后，过滤，滤饼为三溴物，滤液通入过热蒸汽蒸馏，弃去初馏物（含有三溴和一溴物），至内温达155℃以上，收集馏出液，冷却析出结晶而得成品。收率为80%。
  • 用途一:有机合成，制备3,4,5-三甲氧基苯甲醛等。
  • MSDS 信息:2,6-Dibromophenol(608-33-3).msds
  • Hazard Note:Irritant
  • Alfa Aesar:2,6-二溴苯酚,99% 2,6-Dibromophenol, 99%(608-33-3)
  • 图谱信息:2,6-二溴苯酚(608-33-3)核磁图( 1 HNMR) 2,6-二溴苯酚(608-33-3)红外图谱(IR2) 2,6-二溴苯酚(608-33-3)红外图谱(IR1) 2,6-二溴苯酚(608-33-3)核磁图( 13 CNMR) 2,6-二溴苯酚(608-33-3)质谱(MS)
  • 海关编码:29081000
  • MOL 文件:608-33-3.mol
  • 2,6-二溴苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3384 2,6-二溴苯酚 2,6-Dibromophenol 5G 645元 2014/06/02 D3384 2,6-二溴苯酚 2,6-Dibromophenol 25G 2240元 2010/06/21 406520100 2,6-二溴苯酚 2,6-Dibromophenol 99% 10 GR 1508元
  • 2,6-Dibromophenol has been isolated from a luminous marine enteropneust, Balanoglossus biminiensis and is responsible for the characteristic ″iodoform-like″ odor of these animals
  • Acros Organics:2,6-二溴苯酚 2,6-Dibromophenol, 99+%(608-33-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C6 to C8 - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Protected Alcohols/Phenols - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Bromo 溴化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DIA - DIC - D
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers
  1. Medical Research Areas
  2. Metabolism
  3. Endogenous Metabolite  (内源性代谢物)

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