Tris[2-(2-Methoxyethoxy)Ethyl]Amine 三[2-(2-甲氧基乙氧基)乙基]胺
CAS 70384-51-9 MFCD00010748
化学结构图
SMILES: COCCOCCN(CCOCCOC)CCOCCOC
化学属性
| Mol. Formula | C15H33NO6 |
|---|---|
| Mol. Weight | 323 |
| Refractive index | 1.4470 to 1.4490 |
| Density | 1.011 |
| Flash Point | 162°C(lit.) |
| TSCA | Yes |
| Boiling Point | 171°C/1mmHg(lit.) |
| Melting Point | <-100° |
| pH | :A |
别名和识别编码
| Chemical Name | Tris[2-(2-Methoxyethoxy)Ethyl]Amine |
|---|---|
| Synonym | 三[2-(2-甲氧基乙氧基)乙基]胺 |
| PubChem Substance ID | 87577008 |
| EC Number | 274-590-5 |
| Beilstein Registry Number | 2369296 |
| MDL Number | MFCD00010748 |
| CAS Number | 70384-51-9 |
| Chemical Name Translation | 三[2-(2-甲氧基乙氧基)乙基]胺 |
| Reaxys-RN | 2369296 |
| LabNetwork Molecule ID | LN00200475 |
| InChIKey | XGLVDUUYFKXKPL-UHFFFAOYSA-N |
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分类
- {SNA} Amino Alcohols, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- Accelerates dehydrobromination of alkyl halides in the presence of KOH: Org. Synth. Coll., 9, 539 (1998). For use in the Wittig reaction, see Cyclopropyltriphenylphosphonium bromide, B25102.
- In studies of solvent-free SNAr reactions, TDA-1 was found to be the best catalyst: Synth. Commun., 20, 2855 (1990); Heterocycles, 32, 1947 (1991). In combination with CuCl, is also a useful catalyst in the Ullmann aryl ether synthesis: J. Org. Chem., 50, 3717 (1985). An improved N-arylation of amides utilizes a catalyst combination of CuCl and TDA-1 (5:1): Synthesis, 312 (1989).
- Acyclic solid-liquid phase-transfer catalyst (see Appendix 2).
- Has been used in a number of aromatic nucleophilic substitution reactions:
- For use in a stereospecific glycosylation reaction of a pyrimidine base, see: Helv. Chim. Acta, 71, 1573 (1988).
- Solubilizes salts of alkali metals and of transition metals, e.g. PdCl2, RuCl3 and RhCl3, allowing these to be used in hydrogenation reactions: Synth. Commun., 19, 2833 (1989).
- Forms isolable 2:1 complexes with Grignard reagents: Tetrahedron, 45, 171 (1989).
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
其他信息
- 微溶于水。溶于丙酮、醚、甲苯和环己烷。
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