Cobalt(II) acetate tetrahydrate 四水合乙酸钴

CAS 6147-53-1 MFCD00149569

化学结构图

6147-53-1
SMILES: CC(=O)[O-].CC(=O)[O-].O.O.O.O.[Co+2]

化学属性

Mol. FormulaC4H14CoO8
Mol. Weight249.08
Density1.71
Refractive index1.542
TSCAYes
Melting Point140 °C
SolubilitySoluble in water, alcohol, dilute acids

别名和识别编码

Chemical NameCobalt(II) acetate tetrahydrate
Synonym Cobalt(II)acetatetetra hydrate {LY} Cobalt(II)acetatetetra hydrate {} {LY} Cobalt(II)acetatetetra hydrate {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II)acetatetetra hydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II)acetatetetr
Beilstein Registry Number3731397
PubChem Substance ID61372
CAS Number6147-53-1
EC Number200-755-8
MDL NumberMFCD00149569
Merck Number14,2433
Chemical Name Translation四水合乙酸钴
Wiswesser Line NotationOV1 2 &-CO- &QH 4
LabNetwork Molecule IDLN00195085
Canonical SMILES[Co].O=C(O)C.O
InChIInChI=1S/2C2H4O2.Co.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2
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分类

  • {SNA} Cobalt Salts, Essential Chemicals, Research Essentials, Salts
  • {SNA} Essential Chemicals, Inorganic Salts, Solutions and Reagents, Reagent Grade, Research Essentials
  • Cobalt, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • {SNA} Cobalt, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学

相关文献及参考

  • 1. Jaynes, B.S. et al. Inorg. Chem. 34 , 5735, (1995)
  • Merck 14 ,2433
  • Beil. 2 ,IV,120
  • Fieser 4 ,99 / Fieser 16 ,95
  • Aldrich MSDS 1 , 479:C / Corp MSDS 1 (1), 898:A / IR-Spectra (3), 325:B / RegBook 1 (1), 611:E / Sax 6 , 800 / Sigma FT-IR 1 (2), 1021:A / Structure Index 1 , 88:D:1

安全信息

Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P340
  • P304+P341
  • P305+P351+P338
  • P308+P313
  • P308+P316
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P337+P313
  • P342+P311
  • P342+P316
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany2
GHS Symbol
Signal word Danger
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H350 May cause cancer 可能致癌
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Codes 9 T,N Xn Xn;N
RTECSAG3325000
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupIII
UN Number 3077 UN3077
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R38 Irritating to skin 刺激皮肤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R42/43
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R49 May cause cancer by inhalation 吸入会致癌
  • R50/53
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
  • R60 May impair fertility 可能降低生殖能力
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 708 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   20,311,1982

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 600 ug/L
REFERENCE :
   CYGEDX Cytology and Genetics (English Translation).  Translation of TGANAK.
   (Allerton Press Inc., 150 Fifth Ave., New York, NY 10011)  V.8-    1974-
   Volume(issue)/page/year: 12(3),46,1978

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