Aminoacetaldehyde Diethyl Acetal 氨基乙醛二乙缩醛

CAS 645-36-3 MFCD00008136

化学结构图

645-36-3
SMILES: CCOC(CN)OCC

化学属性

Mol. FormulaC6H15NO2
Mol. Weight133.19
Density0.916
Refractive index1.4160 to 1.4190
Boiling Point163°C at 760 mmHg
Flash Point45.6°C
TSCAYes
Solubility可溶
Melting Point-78 °C
pH:A

别名和识别编码

Chemical NameAminoacetaldehyde Diethyl Acetal
Synonym 2,2-Diethoxyethylamine {LY} 2,2-Diethoxyethylamine {} {LY} 2,2-Diethoxyethylamine {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number645-36-3
EC Number211-439-4
Beilstein Registry Number506067
MDL NumberMFCD00008136
PubChem Substance ID69524
Reaxys-RN506067
Chemical Name Translation氨基乙醛二乙缩醛
InChIKeyHJKLEAOXCZIMPI-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009455
InChIInChI=1S/C6H15NO2/c1-3-8-6(5-7)9-4-2/h6H,3-5,7H2,1-2H3
Canonical SMILESNCC(OCC)OCC
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分类

  • {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用于有机合成

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number 1989 2924
Hazard Codes 3
Hazard Class3/8
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Flammables area {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, pr

其他信息

  • Sigma Aldrich:645-36-3(sigmaaldrich)
  • 液体，易溶于水、醇、醚和氯仿。
  • 用途一:用于有机合成。
  • Acros Organics:氨基乙醛二乙缩醛 Aminoacetaldehyde diethyl acetal, 99%(645-36-3)
  • Alfa Aesar:氨基乙醛二乙基缩醛,98% Aminoacetaldehyde diethyl acetal, 98%(645-36-3)
  • 图谱信息:氨基乙醛缩二乙醇(645-36-3)核磁图( 13 CNMR) 氨基乙醛缩二乙醇(645-36-3)核磁图( 1 HNMR) 氨基乙醛缩二乙醇(645-36-3)质谱(MS) 氨基乙醛缩二乙醇(645-36-3)红外图谱(IR1)
  • Hazard Note:Irritant
  • 氨基乙醛缩二乙醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0247 氨基乙缩醛 Aminoacetal 250ML 2580元 2014/06/02 A0247 氨基乙缩醛 Aminoacetal 25ML 386元 2010/06/21 103070050 氨基乙醛缩二乙醇 Aminoacetaldehyde diethyl acetal 99% 5 ML 213元
  • MOL 文件:645-36-3.mol
  • 方法一:由二乙醇缩氯乙醛与氨反应而得。
  • 外观性质:液体，易溶于水、醇、醚和氯仿。沸点：162-163℃闪点:114 °F密度：0.916折光率：1.417
  • 下游产品:8-溴异喹啉 --> 2-硝基咪唑 --> 甲巯咪唑 --> 2-氨基咪唑
  • TCI Shanghai:氨基乙醛缩二乙醇 Aminoacetal,>;97.0%(GC)(T)(645-36-3)
  • 上游原料:二乙醇 --> 氯乙醛
  • MSDS 信息:2,2-Diethoxyethylamine(645-36-3).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Acetals/Ketals/Ortho Esters - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Acetals/Ketals/Ortho Esters - Oxygen Compounds

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