1-丙基磷酸酐 (第二类监控化学品，不能销售)1-丙基磷酸酐
CAS 68957-94-8 MFCD00006583
化学结构图
SMILES: CCCP1(=O)OP(=O)(CCC)OP(=O)(CCC)O1
化学属性
| Mol. Formula | C9H21O6P3 |
|---|---|
| Mol. Weight | 318.18 |
| Refractive index | 1.4190 |
| Boiling Point | 153 |
| Density | 1.09 |
| Flash Point | 62°C(lit.) |
| TSCA | No |
| Appearance | 白色至淡黄液体。 |
| Stability | moisture sensitive |
别名和识别编码
| Chemical Name | 1-丙基磷酸酐 |
|---|---|
| Synonym | 1,3,5,2,4,6-trioxatriphosphorinane,2,4,6-tripropyl-,2,4,6-trioxide 1-PROPANEPHOSPHONIC ACID ANHYDRIDE CYCLIC TRIMER 1-丙基磷酸三环酸酐 1-PROPANEPHOSPHONIC ANHYDRIDE TRIS-N-PROPAN-PHOSPHONIC ACID ANHYDRIDE T3P 2,4,6-Tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide 1-丙基磷酸环酐, 50+% SOLN. IN ETHYL ACETATE Propanephosphonic acid cyclic anhydride (T3P) 1-丙基磷酸环酐, 50+% SOLN. IN DMF 2,4,6-tripropyl-1,3,5-trioxa-2,4,6-triphosphorinane-2,4,6-trioxide 1-丙基磷酸酐 PROPANEPHOSPHONIC ACID CYCLIC ANHYDRIDE 1-Propanephosphonic acid cyclic anhydrideT3P 1-丙基磷酸环酐 溶液 PPACA T3P® 丙基磷酸三环酸酐 溶液 propylphosphonicanhydridesolution 1-丙烷磷酸环酐 1-丙基磷酸环酐 2,4,6-TRIPROPYL-1,3,5,2,4,6-TRIOXATRIPHOSPHORINANE-2,4,6-TRIOXIDE |
| MDL Number | MFCD00006583 |
| PubChem Substance ID | 111923 |
| Beilstein Registry Number | 5079255 |
| CAS Number | 68957-94-8 |
| Reaxys-RN | 5079255 |
| EC Number | 422-210-5 |
| Chemical Name Translation | (第二类监控化学品，不能销售)1-丙基磷酸酐 |
| InChI | InChI=1S/C9H21O6P3/c1-4-7-16(10)13-17(11,8-5-2)15-18(12,14-16)9-6-3/h4-9H2,1-3H3 |
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信息真实价格透明
资金保障
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分类
- {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonic/Phosphinic Acid Anhydrides, Phosphorus Compounds
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonic/Phosphinic Acid Anhydrides, Phosphorus Compounds
相关文献及参考
- Condensation agent in formation of amide and ester linkages. In peptide synthesis, gives high yields, low racemization, and minimization of side reactions without the need for additives, as well as easily removable (water soluble) by-products: Angew. Chem. Int. Ed., 19, 133 (1980). Also reported for formation of a Weinreb amide in high yield from the acid and N,O-dimethylhydroxylamine: Angew. Chem. Int. Ed., 36, 1191 (1997). Activating agent for epoxidation of alkenes, giving cis-stereoselectivity in reactions with allylic alcohols: Tetrahedron Lett., 35, 8125 (1994). For a brief reviews of the reagent, see: Synlett, 1369 (2000); 1328 (2007). For peptide reagents, see Appendix 6.
- For use in the synthesis of N-acyloxythiazole-2(3H)-thiones, see: Synlett, 371 (2000).
- T3P is a registered trademark of Clariant Group.
- T3P is a registered trademark of Archimica.
安全信息
GHS Symbol
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P308+P313
- P304+P340+P310
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P301+P330+P331+P310
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H290 May be corrosive to metals 可能腐蚀金属。
- H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
- H227 Combustible liquid 可燃液体
- R11 Highly flammable 非常易燃
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
- R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
其他信息
- F:21
- 上游原料:盐酸 --> 氧氯化硫 --> 五氯化磷 --> 亚磷酸三乙酯 --> 正丙基溴
- Alfa Aesar:1-丙基磷酸环酐,50+%soln.inethylacetate 1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate(68957-94-8)
- 存储注意事项:湿度敏感;热敏感
- Acros Organics:1-丙烷磷酸环酐 1-Propanephosphonic acid cyclic anhydride, 50 wt.% solution in dimethylformamide(68957-94-8)
- 1-丙基磷酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 429111000 1-丙基磷酸酐 1-Propanephosphonic acid cyclic anhydride , 50 wt.% solution in dimethylformamide, AcroSeal® 100 ML 5119元 2010/06/21 429311000 1-丙基磷酸酐 1-Propanephosphonic acid cyclic anhydride , 50 wt.% solution in ethyl acetate, AcroSeal® 100 ML 4230元 2010/06/21 209010500 1-丙基磷酸酐 1-Propanephosphonic acid cyclic anhydride , 50 wt.% sol. in ethyl acetate 50 ML 1247元
- MOL 文件:68957-94-8.mol
- 敏感性:Moisture Sensitive
- Sigma Aldrich:68957-94-8(sigmaaldrich)
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