Propylphosphonic anhydride 1-丙基磷酸酐

CAS 68957-94-8 MFCD00006583

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H44114
Propylphosphonic anhydride 1-丙基磷酸酐
50% solution in ethyl acetate 5g ¥ 60
50+ % solution 乙酸乙酯
INFI H44114
Propylphosphonic anhydride 1-丙基磷酸酐
50% solution in ethyl acetate 25g ¥ 170
50+ % solution 乙酸乙酯
INFI H44114
Propylphosphonic anhydride 1-丙基磷酸酐
50% solution in ethyl acetate 100g ¥ 561
50+ % solution 乙酸乙酯
INFI H31467
Propylphosphonic anhydride 1-丙基磷酸酐
50% solution in N,N-Dimethylformamide 10g ¥ 130
库存 辽宁
中国国内现货 50+ % solution N,N-二甲基甲酰胺
INFI H31467
Propylphosphonic anhydride 1-丙基磷酸酐
50% solution in N,N-Dimethylformamide 50g ¥ 350
库存 辽宁
中国国内现货 50+ % solution N,N-二甲基甲酰胺
Innochem A29825
2,4,6-Tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide
50wt.% in ethyl acetate 25mL ¥ 276
库存 北京
中国国内现货 50% solution 乙腈
Innochem A29825
2,4,6-Tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide
50wt.% in ethyl acetate 100mL ¥ 720
库存 北京
中国国内现货 50% solution 乙腈
Bellen Bellen00013160
1,3,5,2,4,6-Trioxatriphosphorinane, 2,4,6-tripropyl-,2,4,6-trioxide
96% min 250g ¥ 1,170
96-99 %
Bellen Bellen00013160
1,3,5,2,4,6-Trioxatriphosphorinane, 2,4,6-tripropyl-,2,4,6-trioxide
96% min 500g ¥ 1,950
96-99 %
Bellen Bellen00013160
1,3,5,2,4,6-Trioxatriphosphorinane, 2,4,6-tripropyl-,2,4,6-trioxide
96% min 1kg ¥ 3,510
96-99 %
Bellen Bellen10000223
Propylphosphonic anhydride 1-丙基磷酸酐
5g ¥ 80
Bellen Bellen10000223
Propylphosphonic anhydride 1-丙基磷酸酐
25g ¥ 210
Bellen Bellen10000223
Propylphosphonic anhydride 1-丙基磷酸酐
100g ¥ 700
TCI P1320
Propylphosphonic Acid Anhydride (Cyclic Trimer) (48% in N , N -Dimethylformamide, ca . 1.6mol/L) >
ca. 1.6mol/L) 25g ¥ 550
库存 Tokyo, Japan 北京
中国国内现货 96-99 %
Alfa L19271
1-Propylphosphonic acid cyclic anhydride
50+% soln. in DMF 10g ¥ 262
库存 北京 China, PRC
中国国内现货 50
Alfa L19271
1-Propylphosphonic acid cyclic anhydride
50+% soln. in DMF 50g ¥ 879
库存 北京 China, PRC
中国国内现货 50
Alfa H63583
50+% w/w soln. in dichloromethane 50g ¥ 280
50
Alfa H63583
50+% w/w soln. in dichloromethane 250g ¥ 1,118
50
Alfa H66967
50+% w/w soln. in acetonitrile 50g ¥ 246
50
Alfa H66967
50+% w/w soln. in acetonitrile 250g ¥ 1,028
50
Shao Yuan SY010872
Propylphosphonic Anhydride Solution, 50wt.% in Ethyl Acetate 丙基磷酸三环酸酐, 50wt.%乙酸乙酯溶液
≥50 wt.% (in ethyl acetate) 5g ¥ 65
库存 上海市 济南市
中国国内现货 96-99 %
Shao Yuan SY010872
Propylphosphonic Anhydride Solution, 50wt.% in Ethyl Acetate 丙基磷酸三环酸酐, 50wt.%乙酸乙酯溶液
≥50 wt.% (in ethyl acetate) 10g ¥ 110
库存 上海市 济南市
中国国内现货 96-99 %
Shao Yuan SY010872
Propylphosphonic Anhydride Solution, 50wt.% in Ethyl Acetate 丙基磷酸三环酸酐, 50wt.%乙酸乙酯溶液
≥50 wt.% (in ethyl acetate) 25g ¥ 168
库存 上海市 济南市
中国国内现货 96-99 %
Shao Yuan SY010872
Propylphosphonic Anhydride Solution, 50wt.% in Ethyl Acetate 丙基磷酸三环酸酐, 50wt.%乙酸乙酯溶液
≥50 wt.% (in ethyl acetate) 50g ¥ 299
库存 上海市 济南市
中国国内现货 96-99 %
Shao Yuan SY010872
Propylphosphonic Anhydride Solution, 50wt.% in Ethyl Acetate 丙基磷酸三环酸酐, 50wt.%乙酸乙酯溶液
≥50 wt.% (in ethyl acetate) 100g ¥ 545
库存 上海市 济南市
中国国内现货 96-99 %
Shao Yuan SY010872
Propylphosphonic Anhydride Solution, 50wt.% in Ethyl Acetate 丙基磷酸三环酸酐, 50wt.%乙酸乙酯溶液
≥50 wt.% (in ethyl acetate) 500g ¥ 1,925
库存 上海市
中国国内现货 96-99 %
Shao Yuan SY010872
Propylphosphonic Anhydride Solution, 50wt.% in Ethyl Acetate 丙基磷酸三环酸酐, 50wt.%乙酸乙酯溶液
≥50 wt.% (in ethyl acetate) 1000g ¥ 3,566
96-99 %
Acros 209010500
50 wt.% sol. in ethyl acetate 50mL ¥ 925
库存 北京
中国国内现货 96-99 %
Adamas 76909A
50%+ soln. in ethyl acetate 25g ¥ 158
库存 上海市 China, PRC
中国国内现货 50
Adamas 76909B
50%+ soln. in ethyl acetate 100g ¥ 521
库存 上海市 北京 China, PRC
中国国内现货 50
Strem 15-9159
2,4,6-Tri-n-propyl-2,4,6-trioxo-1,3,5,2,4,6-trioxatriphosphorinane (Propylphosphonic acid anhydride 50% solution in N,N-dimethylformamide) T3P
N-dimethylformamide) TP3 10g ¥ 450
96-99 %
Strem 15-9159
2,4,6-Tri-n-propyl-2,4,6-trioxo-1,3,5,2,4,6-trioxatriphosphorinane (Propylphosphonic acid anhydride 50% solution in N,N-dimethylformamide) T3P
N-dimethylformamide) TP3 50g ¥ 1,455
96-99 %
Strem 15-9160
2,4,6-Tripropyl-2,4,6-trioxo-1,3,5,2,4,6-trioxatriphosphorinane T3P (Propylphosphonic acid anhydride 50% solution in ethyl acetate)
6-trioxatriphosphorinane (Propylphosphonic acid anhydride 50% solution in ethyl acetate) 10g ¥ 450
50
Strem 15-9160
2,4,6-Tripropyl-2,4,6-trioxo-1,3,5,2,4,6-trioxatriphosphorinane T3P (Propylphosphonic acid anhydride 50% solution in ethyl acetate)
6-trioxatriphosphorinane (Propylphosphonic acid anhydride 50% solution in ethyl acetate) 50g ¥ 1,455
50
Matrix 113703
97% 1g ¥ 195
96-99 %
Matrix 113703
97% 5g ¥ 247
96-99 %
Matrix 113703
97% 10g ¥ 1,131
96-99 %
Matrix 113703
97% 25g ¥ 598
库存 北京
中国国内现货 96-99 %
Matrix 113703
97% 100g ¥ 1,762
96-99 %
Matrix 113703
97% 500g ¥ 7,393
96-99 %
HY Y66709
1-Propylphosphonic acid cyclic anhydride 1-丙基磷酸酐
50%+ soln. in ethyl acetate 50g ¥ -
50
Ark AK108387
95+% 10g ¥ 172
96-99 %
Ark AK108387
95+% 25g ¥ 344
96-99 %
Ark AK108387
95+% 100g ¥ 831
96-99 %
Energy-chemical W810223
2,4,6-TRIPROPYL-1,3,5,2,4,6-TRIOXATRIPHOSPHORINANE-2,4,6-TRIOXIDE 1-丙基磷酸酐
50% in N,N-Dimethylformamide, ca. 1.6mol/L 5g ¥ 65
库存 上海市 北京市
中国国内现货 50
Energy-chemical W810223
2,4,6-TRIPROPYL-1,3,5,2,4,6-TRIOXATRIPHOSPHORINANE-2,4,6-TRIOXIDE 1-丙基磷酸酐
50% in N,N-Dimethylformamide, ca. 1.6mol/L 25g ¥ 168
库存 上海市 北京市
中国国内现货 50
Energy-chemical W810223
2,4,6-TRIPROPYL-1,3,5,2,4,6-TRIOXATRIPHOSPHORINANE-2,4,6-TRIOXIDE 1-丙基磷酸酐
50% in N,N-Dimethylformamide, ca. 1.6mol/L 100g ¥ 545
库存 上海市 北京市
中国国内现货 50
Energy-chemical W810225
2,4,6-TRIPROPYL-1,3,5,2,4,6-TRIOXATRIPHOSPHORINANE-2,4,6-TRIOXIDE 1-丙基磷酸酐
50wt.% in Ethyl Acetate 5g ¥ 65
库存 北京市 上海市
中国国内现货 96-99 %
Energy-chemical W810225
2,4,6-TRIPROPYL-1,3,5,2,4,6-TRIOXATRIPHOSPHORINANE-2,4,6-TRIOXIDE 1-丙基磷酸酐
50wt.% in Ethyl Acetate 25g ¥ 168
库存 上海市 北京市
中国国内现货 96-99 %
Energy-chemical W810225
2,4,6-TRIPROPYL-1,3,5,2,4,6-TRIOXATRIPHOSPHORINANE-2,4,6-TRIOXIDE 1-丙基磷酸酐
50wt.% in Ethyl Acetate 100g ¥ 545
库存 上海市 北京市
中国国内现货 96-99 %
Acros 429111000
50 wt.% solution in dimethylformamide 100mL ¥ 1,218
50+ % solution 二甲基甲酰胺
Acros 429311000
50 wt.% solution in ethyl acetate 100mL ¥ 1,197
50+ % solution 乙酸乙酯
Acros 374660250
50 wt.% solution in dimethylformamide 25g ¥ 750
50+ % solution 二甲基甲酰胺
Acros 374661000
50 wt.% solution in dimethylformamide 100g ¥ 2,617
50+ % solution 二甲基甲酰胺
TRC P838245
5g ¥ 2,630
TRC P838245
10g ¥ 1,050
TRC P838245
25g ¥ 3,050
TRC P838245
50g ¥ 2,450
TRC P838245
100g ¥ 5,150
TRC P838245
250g ¥ 10,150
Accela SY010872
N/A 5g ¥ 65
Accela SY010872
N/A 10g ¥ 110
库存 北京
中国国内现货
Accela SY010872
N/A 25g ¥ 168
库存 北京
中国国内现货
Accela SY010872
N/A 50g ¥ 299
库存 北京
中国国内现货
Accela SY010872
N/A 100g ¥ 545
Accela SY010872
N/A 500g ¥ 1,925
Accela SY010872
N/A 1000g ¥ 3,566
Aldrich 431303-10ML
=50 wt. % in ethyl acetate'>>=50 wt. % in ethyl acetate 10mL ¥ 331
Aldrich 431303-50ML
=50 wt. % in ethyl acetate'>>=50 wt. % in ethyl acetate 50mL ¥ 1,064
Aldrich 431303-100ML
=50 wt. % in ethyl acetate'>>=50 wt. % in ethyl acetate 100mL ¥ 2,463
Aldrich 431303-500ML
=50 wt. % in ethyl acetate'>>=50 wt. % in ethyl acetate 500mL ¥ 7,217
Aladdin T189186-5g
50% in N,N-Dimethylformamide 5g ¥ 65
50+ % solution N,N-二甲基甲酰胺
Aladdin T189186-25g
50% in N,N-Dimethylformamide 25g ¥ 168
50+ % solution N,N-二甲基甲酰胺
Aladdin T189186-100g
50% in N,N-Dimethylformamide 100g ¥ 545
50+ % solution N,N-二甲基甲酰胺
Adamas B76909B
1kg ¥ -
Aladdin T189186
1-Propylphosphonic acid cyclic anhydride 1-丙基磷酸环酐
50% in N,N-Dimethylformamide 5g ¥ 65
库存 上海市
中国国内现货 50+ % solution N,N-二甲基甲酰胺
Aladdin T189186
1-Propylphosphonic acid cyclic anhydride 1-丙基磷酸环酐
50% in N,N-Dimethylformamide 25g ¥ 168
库存 上海市
中国国内现货 50+ % solution N,N-二甲基甲酰胺
Aladdin T189186
1-Propylphosphonic acid cyclic anhydride 1-丙基磷酸环酐
50% in N,N-Dimethylformamide 100g ¥ 545
库存 上海市
中国国内现货 50+ % solution N,N-二甲基甲酰胺
Shao Yuan SY263055
Propylphosphonic Anhydride Solution, 50wt.% in DMF 丙基磷酸三环酸酐, 50wt.% DMF溶液
50% 5g ¥ 80
库存 上海市
中国国内现货 50+ %
Shao Yuan SY263055
Propylphosphonic Anhydride Solution, 50wt.% in DMF 丙基磷酸三环酸酐, 50wt.% DMF溶液
50% 10g ¥ 150
库存 上海市
中国国内现货 50+ %
Shao Yuan SY263055
Propylphosphonic Anhydride Solution, 50wt.% in DMF 丙基磷酸三环酸酐, 50wt.% DMF溶液
50% 25g ¥ 245
库存 上海市
中国国内现货 50+ %
Shao Yuan SY263055
Propylphosphonic Anhydride Solution, 50wt.% in DMF 丙基磷酸三环酸酐, 50wt.% DMF溶液
50% 100g ¥ 750
库存 上海市
中国国内现货 50+ %
Accela SY263055
Propylphosphonic anhydride 1-丙基磷酸酐
50% 5g ¥ 80
50+ %
Accela SY263055
Propylphosphonic anhydride 1-丙基磷酸酐
50% 10g ¥ 150
50+ %
Accela SY263055
Propylphosphonic anhydride 1-丙基磷酸酐
50% 25g ¥ 245
50+ %
Accela SY263055
Propylphosphonic anhydride 1-丙基磷酸酐
50% 100g ¥ 750
50+ %

分类

  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonic/Phosphinic Acid Anhydrides, Phosphorus Compounds
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonic/Phosphinic Acid Anhydrides, Phosphorus Compounds

相关文献及参考

  • Condensation agent in formation of amide and ester linkages. In peptide synthesis, gives high yields, low racemization, and minimization of side reactions without the need for additives, as well as easily removable (water soluble) by-products: Angew. Chem. Int. Ed., 19, 133 (1980). Also reported for formation of a Weinreb amide in high yield from the acid and N,O-dimethylhydroxylamine: Angew. Chem. Int. Ed., 36, 1191 (1997). Activating agent for epoxidation of alkenes, giving cis-stereoselectivity in reactions with allylic alcohols: Tetrahedron Lett., 35, 8125 (1994). For a brief reviews of the reagent, see: Synlett, 1369 (2000); 1328 (2007). For peptide reagents, see Appendix 6.
  • For use in the synthesis of N-acyloxythiazole-2(3H)-thiones, see: Synlett, 371 (2000).
  • T3P is a registered trademark of Clariant Group.
  • T3P is a registered trademark of Archimica.

安全信息

GHS Symbol
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P308+P313
  • P304+P340+P310
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P301+P330+P331+P310
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H227 Combustible liquid 可燃液体
Hazard Codes T
WGK Germany2
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word
UN Number UN 2924 3/PG 3 UN2924 3265
Risk Statements
  • R11 Highly flammable 非常易燃
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Storage condition Moisture Sensitive Flammables area
Packing GroupII
Hazard Class8

其他信息

  • F:21
  • 上游原料:盐酸 --> 氧氯化硫 --> 五氯化磷 --> 亚磷酸三乙酯 --> 正丙基溴
  • Alfa Aesar:1-丙基磷酸环酐,50+%soln.inethylacetate 1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate(68957-94-8)
  • 存储注意事项:湿度敏感;热敏感
  • Acros Organics:1-丙烷磷酸环酐 1-Propanephosphonic acid cyclic anhydride, 50 wt.% solution in dimethylformamide(68957-94-8)
  • 1-丙基磷酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 429111000 1-丙基磷酸酐 1-Propanephosphonic acid cyclic anhydride , 50 wt.% solution in dimethylformamide, AcroSeal® 100 ML 5119元 2010/06/21 429311000 1-丙基磷酸酐 1-Propanephosphonic acid cyclic anhydride , 50 wt.% solution in ethyl acetate, AcroSeal® 100 ML 4230元 2010/06/21 209010500 1-丙基磷酸酐 1-Propanephosphonic acid cyclic anhydride , 50 wt.% sol. in ethyl acetate 50 ML 1247元
  • MOL 文件:68957-94-8.mol
  • 敏感性:Moisture Sensitive
  • Sigma Aldrich:68957-94-8(sigmaaldrich)

化学结构图

CAS 68957-94-8  MFCD00006583
SMILES: CCCP1(=O)OP(=O)(CCC)OP(=O)(CCC)O1

化学属性

Mol. FormulaC9H21O6P3
Mol. Weight318.18
Refractive index1.4190
Boiling Point153
Density1.09
Flash Point62°C(lit.)
TSCANo
Appearance 白色至淡黄液体。
Mol. FormulaC9H21O6P3
Mol. Weight318.20
Appearance slightly yellow to brown liq.
Stabilitymoisture sensitive

别名和识别编码

Chemical NamePropylphosphonic anhydride
Synonym 1,3,5,2,4,6-trioxatriphosphorinane,2,4,6-tripropyl-,2,4,6-trioxide 1-PROPANEPHOSPHONIC ACID ANHYDRIDE CYCLIC TRIMER 1-丙基磷酸三环酸酐 1-PROPANEPHOSPHONIC ANHYDRIDE TRIS-N-PROPAN-PHOSPHONIC ACID ANHYDRIDE T3P 2,4,6-Tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide 1-丙基磷酸环酐, 50+% SOLN. IN ETHYL ACETATE Propanephosphonic acid cyclic anhydride (T3P) 1-丙基磷酸环酐, 50+% SOLN. IN DMF 2,4,6-tripropyl-1,3,5-trioxa-2,4,6-triphosphorinane-2,4,6-trioxide 1-丙基磷酸酐 PROPANEPHOSPHONIC ACID CYCLIC ANHYDRIDE 1-Propanephosphonic acid cyclic anhydrideT3P 1-丙基磷酸环酐 溶液 PPACA T3P® 丙基磷酸三环酸酐 溶液 propylphosphonicanhydridesolution 1-丙烷磷酸环酐 1-丙基磷酸环酐 2,4,6-TRIPROPYL-1,3,5,2,4,6-TRIOXATRIPHOSPHORINANE-2,4,6-TRIOXIDE
MDL NumberMFCD00006583
PubChem Substance ID111923
Beilstein Registry Number5079255
CAS Number68957-94-8
Reaxys-RN5079255
EC Number422-210-5
Chemical Name Translation1-丙基磷酸酐
InChIInChI=1S/C9H21O6P3/c1-4-7-16(10)13-17(11,8-5-2)15-18(12,14-16)9-6-3/h4-9H2,1-3H3
MDL NumberMFCD00006583
CAS Number68957-94-8

系列性分类


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